Results 141 to 150 of about 5,339 (237)

A PLP‐SEC Investigation of Di(Ethylene Glycol) Methyl Ether Methacrylate Radical Polymerization Propagation Kinetics in Solution

open access: yesMacromolecular Reaction Engineering, EarlyView.
The propagation rate coefficient of di(ethylene glycol) methyl ether methacrylate exhibits the same temperature dependency but is a factor of 12 higher in aqueous solution compared to bulk. Smaller increases are observed in ethanol and ethanol/water mixtures, with the value of the rate coefficient decreasing as the monomer concentration in solution is ...
Fatemeh Salarhosseini   +1 more
wiley   +1 more source

Sustainable Composites From Almond Shell Powder and Recycled Polyolefin Blends: Effect of Compatibilizer on Interfacial Adhesion and Properties

open access: yesPolymer Composites, EarlyView.
Schematic illustration of sustainable recycled polyolefin/almond shell composites showing the effect of MA‐g‐PP compatibilizer on interfacial adhesion, void reduction, and composite morphology for lightweight automotive applications. ABSTRACT This study reports injection‐molded sustainable composites developed from a hybrid recycled polymer matrix ...
Rebecca Sanchez   +4 more
wiley   +1 more source

Potential of Thermoset Polyolefins for FRP Concrete Reinforcing Bars

open access: yesPolymer Composites, EarlyView.
Overview of XLPO and pDCPD resins for FRP reinforcing bars, highlighting resin chemistry, key performance characteristics, fiber sizing interactions, and principal degradation mechanisms in concrete environments. ABSTRACT Although thermoset polyolefins offer resistance to hydrolytic degradation and favorable processing characteristics, their potential ...
Osama Omar   +5 more
wiley   +1 more source

Pretreatment Effects of Conventional and Reactive Extrusion on LLDPE Waste Pyrolysis

open access: yesPolymer Engineering &Science, EarlyView.
Schematic overview of the pyrolysis study using original and pretreated LLDPE waste samples. Pretreatment was performed via twin‐screw extrusion at 450°C: without additives (REX), with peroxide (REX‐RO2), or with polypropylene (REX–PP). All four samples underwent pyrolysis at 450°C–475°C for 15–45 min.
Yasmin Fialho Siqueira   +8 more
wiley   +1 more source

Diverse reactivity of maleimides in polymer science and beyond

open access: yesPolymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick   +2 more
wiley   +1 more source

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

Characteristics, properties and limitations of per‐ or polyfluoroalkyl substances (PFASs) and fluoropolymers

open access: yesPolymer International, EarlyView.
An overview and categorization of man‐made per‐ or polyfluoroalkyl substances (PFASs) including low‐molar‐mass and high‐molar‐mass fluorochemicals, and their international regulations is presented. Though certain PFASs are toxic, bioaccumulative and cross the human cellular membranes, others, such as fluoropolymers, are safe, reliable and involved in ...
Bruno Améduri
wiley   +1 more source

Unsaturated biobased polyesters from bicyclic α‐pinene‐based diols

open access: yesPolymer International, EarlyView.
We present the synthesis of four biosourced unsaturated polyesters made from chiral terpene‐based diols and esters of renewable diacids. The resulting materials harbor a bicyclic pinene ring in their backbones which leads to enhanced thermal properties while still conferring susceptibility to enzyme hydrolysis for chains having a cis alkene.
Ganapathy Ranjani   +4 more
wiley   +1 more source

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