Transition Metal Catalysis on Olefins: Some Considerations Relative to Migratory Insertion
Olefin migratory insertion into a metal–hydrogen or a metal–carbon bond is an ubiquitous step in olefin coordination catalysis by transition metal complexes. When the catalytic system has element(s) of chirality, and when the two carbon atoms of
Giambattista Consiglio
doaj
Une grande variété de complexes de métaux de transition, homogènes ou hétérogènes, sont susceptibles de provoquer la scission des doubles et triples liaisons carbone-carbone.
Chauvin Y., Commereuc D.
doaj +1 more source
Parallel Catalyst Synthesis Protocol for Accelerating Heterogeneous Olefin Polymerization Research. [PDF]
Chammingkwan P +3 more
europepmc +1 more source
Modeling and Simulation of Olefin Polymerization at Microstructure Level [PDF]
A new model based on a combination of the polymeric multigrain and multilayer models has been developed to predict the polymerization rate, particle growth, morphology, effective parameters on broadening of the molecular weight distribution, number and ...
Ali Dashti, Ahmad Ramazani S.A.
doaj
Magnesium alkoxide precursor to Ziegler-Natta catalyst - emphasis on morphology studies through computer vision approach [PDF]
MgCl2 supported Ti catalyst is used in commercial propylene polymerization process. Morphology is a key performance determination parameter for polymer resins produced by commercial olefin polymerization process. Higher resin flowability and bulk density
Yogeshwar Thakare +5 more
doaj +1 more source
Super Active Catalyst for Olefin Polymerization [PDF]
Study to get a high activity for olefin polymerization by a supporting Ziegler-type catalyst on MgCl2 was carried out. Only heating anhydrous MgCl2 with TiCl4, very little amount of TiCl4 was fixed because of high crystallinity and small surface of anhydrous MgCl2.
openaire +1 more source
A Hydrocarbon Soluble, Molecular and "Complete" Al-Cocatalyst for High Temperature Olefin Polymerization. [PDF]
Urciuoli G +8 more
europepmc +1 more source
Toward Chromoselective Transformations in Biological Systems: Perspectives and Challenges
Controlling biological systems with small‐molecule chromophores has evolved into a powerful strategy and is applied from chemical biology to medicine. However, the complexity of in vivo systems cannot be matched by a single wavelength of light. Developing methods to combine and individually control multiple chromophores is crucial.
Nadja A. Simeth
wiley +1 more source
Polyolefin reweaved ultra-micropore membrane for CO2 capture
High-performance gas separation membranes have potential in industrial separation applications, while overcoming the permeability-selectivity trade-off via regulable aperture distribution remains challenging.
Xiuling Chen +6 more
doaj +1 more source
Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics. [PDF]
Dall'Anese A +11 more
europepmc +1 more source

