Results 161 to 170 of about 12,589 (233)

Self‐Assembled Luminescent Au(I)–Adamantylamine Coordination Polymer Needles With Thermoresponsive Optical Properties

open access: yesChemistry – A European Journal, EarlyView.
A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado   +4 more
wiley   +1 more source

Isoelectronic Alloying in Zintl Phases Mediated the Avoided Crossing and Phonon Softening

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A small amount of Hf doping endows Zr3Ni3Sb4‐Zintl with an unusually low thermal conductivity far exceeding that of similar systems. Two unique phonon mechanisms—avoided crossing and phonon softening—significantly suppress the lattice thermal conductivity. The average thermoelectric figure of merit is improved by 21%.
Zesong Wang   +6 more
wiley   +1 more source

Cobalt‐Free Single‐Crystal Cathodes for Next‐Generation Lithium‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Cobalt‐free single‐crystal cathodes enhance lithium‐ion battery stability by mitigating fracture, degradation, and phase transitions. This review highlights Ni‐rich layered, Li‐Mn‐rich, spinel, and olivine frameworks, synthesis strategies enabling morphology and defect control, and structural tuning via doping and coatings, offering pathways toward ...
Srinivasan Alagar   +5 more
wiley   +1 more source

Ultra‐High Strength and Environmentally Stable Fluorinated Solid‐State Ion‐Conductive Elastomers with Folding‐Paper‐Structured Triboelectric Nanogenerators for Wave Energy Harvesting

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this work, a polyurethane‐based fluorinated SICEs with excellent mechanical properties (7.35 MPa and 61.4 MJ m−3), conductivity (4.2 × 10−4 S cm−1), and harsh environmental resistance were prepared by a “three birds with one stone” strategy that combines multiple interactions with fluorine effects. The paper‐folding TENG is capable of harvesting not
Zequan Li   +9 more
wiley   +1 more source

Bottlenecks‐Breaking in Zinc‐Iodine Batteries Toward Practical Implementation: A Review and Perspective

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Aqueous zinc–iodine batteries (Zn–I2Bs) offer promise for grid storage due to safety and cost advantages yet face critical bottlenecks: severe self‐discharge (polyiodide shuttling and HER), limited energy density, sluggish kinetics, and zinc anode instability.
Jia‐Lin Yang   +3 more
wiley   +1 more source

Hydrophobic eutectic solvent‐engineered membranes for highly permeable, selective, and antifouling pharmaceutical removal from municipal wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Single‐step incorporation of a hydrophobic deep eutectic solvent (HDES) into polyethersulfone ultrafiltration membranes via non‐solvent induced phase separation creates selective, antifouling membranes for pharmaceutical removal. The HDES nanodomains enhance permeability, electrostatic interactions, and adsorption affinity, enabling efficient and ...
Anjali Goyal   +8 more
wiley   +1 more source

Water balloon-induced orbital fracture in an aviator. [PDF]

open access: yesMil Med Res, 2019
Holland TE   +3 more
europepmc   +1 more source

Enabling High‐Loading Aqueous Zinc–Sulfur Batteries Via a Ni Single‐Atom Catalytic Host with Hierarchical Sulfur Reservoirs

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A Ni single‐atom‐anchored N‐doped carbon hollow host synergizes atomic Ni‐N4 sites with a hierarchical porous skeleton, enabling high‐sulfur‐loading aqueous Zn–S batteries with high capacity, low polarization, and excellent cycling stability for flexible energy storage.
Zuoshu Wang   +4 more
wiley   +1 more source

Interfacial Solvent Molecular Engineering via High‐Safety Dense Separators for High‐Rate Lithium‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The dense PPS‐separator prevents thermal runaway by allowing electron transfer through the steel needle during penetration, while the residual electrolyte enables brief ion migration and Joule heating, causing rapid electrolyte vaporization, collapse of the ion transport network, and a sharp drop in ionic conductivity.
Haitao Zhou   +10 more
wiley   +1 more source

Rigid Ligand Environments at Beryllium, From Spectroscopic Probes to Small Molecule Activation

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Due to the high rigidity and definition of beryllium scorpionate complexes, they can be used to study metal‐pseudohalide and ‐carbon bonds in detail. Furthermore, these compounds can be used to activate small molecules and exhibit unprecedented transmetalation reactions. In beryllium scorpionate complexes, three of the four available coordination sites
Magnus R. Buchner, Chantsalmaa Berthold
wiley   +1 more source

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