Results 241 to 250 of about 18,225 (302)

Predictive Registry Optimization of Molecular Adsorbates on Solid Surfaces

open access: yesAngewandte Chemie, EarlyView.
Local C–H “spikes” from a π‐conjugated backbone lock into graphene “pockets”. A geometric registry score turns images obtained by scanning tunneling microscopy at the solid/liquid interface into atomic‐scale adsorption models, enabling assignment of surface atropisomers in large π‐conjugated molecules.
David A. Hofmeister   +7 more
wiley   +2 more sources

A Neuromorphic Simulation Framework for Indium‐Gallium‐Zinc‐Oxide Charge‐Trap Synaptic Transistors: From Device Modeling to System Simulation

open access: yesAdvanced Intelligent Systems, EarlyView.
This work presents a comprehensive framework bridging device fabrication, modeling, and system‐level simulation for an indium‐gallium‐zinc‐oxide (IGZO) charge‐trap synaptic transistor‐based neuromorphic system. By developing a precise SPICE model derived from fabricated IGZO synaptic transistors, the study incorporates parasitic RC loads into array ...
Yumin Yun   +5 more
wiley   +1 more source

Wet Transfer of In Situ Grown Azo‐Containing Two‐Dimensional Conjugated Covalent Organic Framework Films for Photoswitchable Electronic Devices

open access: yesAngewandte Chemie, EarlyView.
Wet transfer of an atomically flat azo‐functionalized 2D covalent organic framework film onto monolayer MoS2 enables clean van der Waals heterostructure devices with reversible photoswitching and multilevel nonvolatile memory. ABSTRACT Two‐dimensional π‐conjugated covalent organic frameworks (2D π‐COFs) combine in‐plane π‐delocalization with periodic ...
Kexin Wang   +11 more
wiley   +2 more sources

Neuromorphic Denoising with Fully Analog Memristive In‐Memory Computing

open access: yesAdvanced Intelligent Systems, EarlyView.
This article borrows the concepts of episodic memory in human brains to experimentally implement a memristor‐based neuromorphic denoising process. A homogeneous memristor processing unit is experimentally demonstrated for both temporal storage and neural network computation, imitating the synapses in the human brain.
Daijing Shi   +5 more
wiley   +1 more source

Ultra‐Thin and Highly Insulating Aromatic Monolayers by N‐Heterocyclic Carbenes

open access: yesAngewandte Chemie, EarlyView.
By using N‐heterocyclic carbenes extremally insulating and at the same time as thin as 0.3 nm molecular films are formed. The charge transport calculations indicate absence of destructive quantum interference effect which was so far the only way to suppress conductivity in aromatic molecules.
Mateusz Wróbel   +6 more
wiley   +2 more sources

Boosting Photocatalytic Overall Water Splitting Activity of Phosphorene Through Five‐Coordinate Passivation Enabled by Carbene Addition

open access: yesAngewandte Chemie, EarlyView.
We report selective five‐coordinate passivation of phosphorene via P═C double bonds using a facile one‐step photochemical reaction via carbene addition. The ambient stability of functionalized phosphorene has been substantially improved compared to the pristine phosphorene.
He Zhang   +12 more
wiley   +1 more source

Stabilizing the Hexacyanotrimethylenecyclopropane Electron Acceptor—Structural and Photophysical Characterization

open access: yesAngewandte Chemie International Edition, EarlyView.
An improved low‐temperature synthesis enables the first comprehensive structural and spectroscopic characterisation of neutral hexacyanotrimethylenecyclopropane (CN6CP). Combined IR/Raman, UV–Vis and ssNMR analyses reveal a deeper understanding of its oxidation‐state‐dependent charge redistribution, σ‐aromaticity of the cyclopropane core, and redox ...
Jan P. Soyka   +8 more
wiley   +1 more source

A Fixed‐Charge Interphase Synchronizes Ion Transport to Suppress Space‐Charge‐Driven Inefficiency Under Nanoliter Confinement

open access: yesAngewandte Chemie International Edition, EarlyView.
Electrochemical energy storage breaks down under extreme miniaturization, where interfaces and space‐charge dominate device behavior. This work introduces a fixed‐charge selective interphase (FCSI) integrated into a twin‐tube micro‐Swiss‐roll architecture.
Yaping Yan   +12 more
wiley   +1 more source

Molecular Dioxygen‐Mediated Passivation of Electron Traps in n‐Type Organic Charge‐Transfer Complexes

open access: yesAngewandte Chemie International Edition, EarlyView.
O2 enhances charge‐transfer in n‐type organic donor–acceptor charge‐transfer complexes (CTCs) via physisorption‐mediated trap passivation. By suppressing recombination and promoting long‐lived delocalized charge carriers, O2 improves electron transport and conductivity without doping.
Kirill K. Gubanov   +16 more
wiley   +1 more source

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