Predictive, Data-Driven Design of Red-Light Photoredox Catalysts for C─Heteroatom Bond Formation. [PDF]
Gizatullin A +6 more
europepmc +1 more source
On the Reaction Mechanism of Nitrate Radical and DMPO in Non‐aqueous Photocatalytic Media
This work identifies 2‐oxo‐5,5‐dimethyl‐1‐pyrroline 1‐oxyl (DMPOX), formed via the selective oxidation of 5,5‐dimethyl‐1‐pyrroline N‐oxide (DMPO) by nitrate radicals (NO3•) in nonaqueous media, as a distinctive EPR fingerprint of NO3•. The DFT‐supported mechanism clarifies its formation pathway and highlights DMPOX detection as a robust tool for ...
Alessandro Gottuso +4 more
wiley +1 more source
Recent advances in boosting interfacial bubble dynamics with external fields
External physical fields, including acoustic, magnetic, thermal, mechanical, and optical stimuli, accelerate the entire bubble‐dynamics sequence of nucleation, growth, and detachment. Abstract The efficiency of industrial electrocatalytic reactions depends not only on generating gaseous products but also on their detachment from the catalyst surface ...
Wenlu Xie +5 more
wiley +1 more source
Decoration of MnFe<sub>2</sub>O<sub>4</sub> nanoparticles on activated carbon as recoverable photocatalyst for perfluorooctanesulfonic acid degradation in water. [PDF]
Trung Kien N +9 more
europepmc +1 more source
The MIL‐125‐NH2(Ti)/WO3‐x S‐scheme heterostructure was constructed via electrostatic self‐assembly, strategically aligning energy bands to optimize interfacial charge transfer and ·OH generation for C–H activation. The optimized MW‐3 demonstrates exceptional CH4 photooxidation activity using water vapor as a sustainable oxidant, achieving a remarkable ...
Jia‐Min Cao +8 more
wiley +1 more source
α,β-Unsaturated (Bis)Enones as Valuable Precursors in Innovative Methodologies for the Preparation of Cyclic Molecules by Intramolecular Single-Electron Transfer. [PDF]
Benettin T +4 more
europepmc +1 more source
Decatungstate-based photocatalysts for organic transformations
Yurui Li +5 more
openaire +1 more source
2D/2D MOF‐Based S‐Scheme Photocatalyst for Enhanced H2 Production and Charge Transfer
An ultrathin 2D/2D MOF‐based S‐scheme heterojunction is constructed via pH‐mediated electrostatic self‐assembly, generating a built‐in electric field that accelerates interfacial charge separation while preserving strong redox potentials. This design enables highly efficient cocatalyst‐free photocatalytic hydrogen evolution.
Chuanbiao Bie, Jiaguo Yu
wiley +1 more source
Photocatalytic coupling of phenols with imines <i>via</i> polarity reversal.
Liu CR, Sojdak CA, Kozlowski MC.
europepmc +1 more source
Design and Experimental Validation of a Photocatalyst Recommender Based on a Large Language Model. [PDF]
Millward F +13 more
europepmc +1 more source

