Results 121 to 130 of about 96,403 (305)

The Electrochemical Oxidation of Organic Selenides and Selenoxides [PDF]

open access: yes, 1997
The electrochemical oxidation of alkyl and aryl selenides was investigated in acetonitrile. The oxidation of diphenyl selenide and di(4‐methylphenyl) selenide led primarily to the formation of their respective selenoxides, which were identified by ...
Hack, Michael   +2 more
core   +1 more source

Enhancing Li‐S Battery Performance Through Low‐Concentration Electrolytes with Organic Se/Te Co‐Additives to Address Solubility and Kinetic Challenges

open access: yesAdvanced Science, EarlyView.
This work presents a low‐concentration electrolyte enabled by hybrid organic Se/Te additives (DPDSe/DPDTe) that restructures solvation, boosts polysulfide dissolution, and provides dual‐site synergistic catalysis, delivering high capacity and stable cycling in Li–S coin and pouch cells, supporting high‐energy, high‐power operation.
Ruihua Li   +10 more
wiley   +1 more source

Effects of different selenium fertilizer types and dosages on non-volatile organic acids and aroma substances of flue-cured tobacco

open access: yesFrontiers in Plant Science
Tobacco (Nicotiana tabacum L.) is well-known as an economic crop whose quality is evaluated according to its aroma quality. Researchers have found that selenium application can increase the aroma quality of tobacco, but until now, its mechanism is still ...
Wanhui Jiang   +9 more
doaj   +1 more source

Quantum Dots for Biomedical Biosensing, NIR‐II Bioimaging, and Phototherapy: Materials Design, Signal Transduction, and Translational Barriers

open access: yesAdvanced Science, EarlyView.
This review outlines bottom‐up and biomimetic fabrication strategies of quantum dots, and highlights their emerging applications in biosensing, multimodal bioimaging, and intelligent cancer theranostics. It further discusses key translational barriers and future perspectives for advancing QD‐based nanomedicine toward clinical implementation.
Jie Ju   +5 more
wiley   +1 more source

Alkyltransferase Ribozyme for Site‐Specific N4‐Cytidine Alkylation

open access: yesAngewandte Chemie, EarlyView.
CSAR is the first ribozyme that catalyzes direct alkylation of an exocyclic amino group of an RNA nucleobase. The ribozyme was isolated as a self‐labeling catalyst from an in vitro selection library and engineered into a trans‐active ribozyme that catalyzes the transfer of a benzyl group from an O6‐modifed guanine to the N4 amino group of a specific ...
Evgeniia Dorinova   +2 more
wiley   +2 more sources

Modeling and Verification of 1/f Noise Mechanisms in FAPbBr3 Single‐Crystal X‐Ray Detectors

open access: yesAdvanced Electronic Materials, EarlyView.
We demonstratethat surface‐trap‐induced carrier number fluctuations are the dominantmechanism in FAPbBr3 Schottky devices, a conclusion supported by thedistinct defect profiles revealed by Drive‐Level Capacitance Profiling (DLCP). Throughnoise contribution decomposition, it is found that the 1/f noise of thedetector is the key noise source affecting ...
Zhongyu Yang   +6 more
wiley   +1 more source

1,4‐Digermacyclopenta‐1,3‐diene: Continuous Cyclic σ*–π Delocalization Enables Aromatic Stabilization in a Heavy‐Element 4π System

open access: yesAngewandte Chemie, EarlyView.
A five‐membered digermacycle exhibits an unusual 4π electron delocalization enabled by σ*(Ge–C)–π coupling within a nearly planar framework. Combined experimental and theoretical analyses reveal a continuous cyclic delocalization pathway, highlighting σ*–π interactions as a design principle for aromatic stabilization beyond classical π‐conjugated ...
Daichi Uchida   +2 more
wiley   +2 more sources

Recent Advances in Nano‐Microstructured Catalysts for Electrochemical Seawater Electrocatalysis

open access: yesAdvanced Energy Materials, EarlyView.
This review highlights advances in nano‐ and microstructured catalysts for electrochemical seawater conversion. It elucidates design principles, mechanistic understanding, and machine‐learning‐assisted discovery, and outlines key challenges and future opportunities toward efficient, selective, and durable seawater electrocatalysis.
Xiaodong Shao   +5 more
wiley   +1 more source

Coupling Electrochemical CO2 Reduction With Ethanol Oxidation for Acetate Production in a Dual‐Electrolyzer System

open access: yesAngewandte Chemie, EarlyView.
A tandem cell system coupling electrochemical CO2 reduction and electrochemical ethanol oxidation is demonstrated for overall acetate production, providing concepts for a CO2‐negative bioethanol to acetate pathway. ABSTRACT Bioethanol production from biomass is suggested as a strategy for greener fuel production.
Anirudha Shekhawat   +5 more
wiley   +2 more sources

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