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The Persistent Radical Effect in Organic Synthesis.

Angewandte Chemie, 2019
Radical-radical couplings are mostly nearly diffusion controlled processes. Therefore, the selective cross-coupling of two different radicals is challenging and not a synthetically valuable process.
Dirk Leifert, A. Studer
semanticscholar   +1 more source

Broadening the Scope of Biocatalysis in Sustainable Organic Synthesis.

ChemSusChem, 2019
This Review is aimed at synthetic organic chemists who may be familiar with organometallic catalysis but have no experience with biocatalysis, and seeks to provide an answer to the perennial question: if it is so attractive, why wasn't it extensively ...
R. Sheldon, D. Brady
semanticscholar   +1 more source

Recent Advances in Pyridinium Salts as Radical Reservoirs in Organic Synthesis

ACS Catalysis, 2019
Pyridinium salts are valuable building blocks, which have been widely applied in various organic transformations during the past few decades. In particular, N-functionalized pyridinium salts have been explored as convenient radical precursors, which ...
F. He, Shengqing Ye, Jie Wu
semanticscholar   +1 more source

Transition Metal Vinylidene- and Allenylidene-Mediated Catalysis in Organic Synthesis.

Chemical Reviews, 2019
With their mechanistic novelty and various modalities of reactivity, transition metal unsaturated carbene (alkenylidene) complexes have emerged as versatile intermediates for new reaction discovery. In particular, the past decade has witnessed remarkable
Sang Weon Roh   +2 more
semanticscholar   +1 more source

Organic Synthesis

2011
Organic synthesis is a vibrant and rapidly evolving field; we can now cyclize amines directly onto alkenes. Like the first two books in this series, Organic Synthesis: State of the Art 2003-2005 and Organic Synthesis: State of the Art 2005-2007, this reference leads readers quickly to the most important recent developments.
openaire   +1 more source

α-Keto Acids: Acylating Agents in Organic Synthesis.

Chemical Reviews, 2019
A significant number of important acyl-transfer reactions, such as direct acylation, ortho acylation, heteroatom acylation, and a diversity of cyclization reactions using the title compound as a key starting material, have been described in recent years.
Filipe Penteado   +5 more
semanticscholar   +1 more source

Selenium in Organic Synthesis

Science, 1986
The introduction, manipulation, and ultimate removal of selenium-containing functional groups allow a variety of synthetically useful processes to be accomplished in high overall yields under mild conditions. In particular, transformations such as allylic oxidations, nucleophile-induced cleavage reactions, regiospecific alkylations, and olefin ...
Dennis, Liotta, Robert, Monahan
openaire   +2 more sources

Synergistic Pd/Cu Catalysis in Organic Synthesis.

Chemistry, 2019
Synergistic Pd/Cu catalysis has been utilized in the Sonogashira reaction since 1975. However, this strategy has not received much attention from organic chemist community until recently.
Yue Wu, Xiaohong Huo, Wanbin Zhang
semanticscholar   +1 more source

Hydrophobically Directed Organic Synthesis

Angewandte Chemie International Edition, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Ulf M, Lindström, Fredrik, Andersson
openaire   +2 more sources

Organic Synthesis on Graphene

Accounts of Chemical Research, 2012
Graphene is a two-dimensional crystalline carbon allotrope that has fascinated researchers worldwide and has extended the interest in carbon structures such as fullerenes and nanotubes. In this Account, we use electrical characterization tools to study chemistry on supported graphene.
Fabian M, Koehler, Wendelin J, Stark
openaire   +2 more sources

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