Results 101 to 110 of about 62,479 (238)

Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne

Angewandte Chemie International Edition, EarlyView.
Technetium alkyne complexes have eluded isolation for decades with the only indicators for their existence being the isolation of vinylidene carbenes or their follow‐up reaction products despite plentiful of reports for neighboring elements. Stable, crystalline Tc(III) and Tc(V) alkyne complexes (and their Re analogs) have now been prepared and fully ...
Maximilian Roca Jungfer, Moritz Johannes Ernst, Lukas Eberle, Marius Kesselring, Guilhem Claude, Joachim Ballmann   +5 more
wiley   +1 more source

III. Organometallic and Bioorganometallic Chemistry - Ferrocene Peptides [PDF]

Kemija u Industriji, 2012
This paper is devoted to the bioconjugates of ferrocene with naturally occuring amino acids/peptides - mostly dealing with authors' results accompanied, to a lesser degree, by the relevant literature data. Chapter 2 deals with
Kovačević, M., Rapić, V.
doaj  

Novel "green" catalysts for controlled ring-opening polymerization of lactide [PDF]

, 2010
Syntéza polylaktidu (PLA) polymerací za otevření kruhu cyklického monomeru (ROP) může být uskutečněna různými způsoby. Literatura uvádí více než 100 katalytických systémů, jejichž pomocí lze polylaktid a jiné biodegradabilní alifatické polyestery získat.
Surman, František
core  

Synthesis and characterization of nickel polycyclic aromatic carbon compounds [abstract] [PDF]

, 2006
only availableFaculty Mentor: Paul R. Sharp, 125 ChemistryPolycyclic aromatic carbon (PAC) compounds show useful chemical, biological, photophysical, electrical, structural and magnetic properties.
Galustyan, Arsen, Sharp, Paul Ray
core  

Reduction of CO2 and Related Compounds with a Low‐Valent CaI Synthon

ChemistryEurope
The reduction of CO2 with low‐valent s‐block metal complexes is limited to MgI reducing agents. Herein, the reduction of a series of CX2 reagents (X = O, S, NiPr) with the CaI synthon [(BDI)Ca(THP)]2(N2) (VI) is described, which is a CaII complex that ...
Stefan Thum, Jonathan Mai, Neha Patel, Jens Langer, Sjoerd Harder   +4 more
doaj   +1 more source

N‐heterocyclic carbene‐based tetradentate Pt(II) phosphors for blue organic light‐emitting diodes: Molecular design, photophysics, and device performance

Bulletin of the Korean Chemical Society, EarlyView.
Structure‐oriented design of NHC‐based tetradentate Pt(II) complexes offers narrowband deep‐blue emission for OLEDs. This review highlights how steric shielding and electronic modulation regulate intermolecular interactions, excited‐state dynamics, and device performance, outlining design principles and outlines toward efficient and durable blue ...
Mingi Kim, Chan Hee Ryu, Kang Mun Lee
wiley   +1 more source

Boosting Electron‐Hole Charge Separation in CO2 Photoreduction through Fluoroporphyrin‐Linked Nickel(II)‐Acetylide Frameworks

Carbon Energy, EarlyView.
A NiII‐acetylide framework, H2TFPP‐Ni‐AF, demonstrates outstanding photocatalytic CO2 reduction performance: 13.16 mmol h−1 g−1 of CO with 97.9% selectivity. Synergistic interactions, including d‐p orbital hybridization within NiII‐bis(acetylide) moieties ( − C ≡ C−NiII(PBu3)2 − C ≡ C − ) and the efficient charge transport afforded by π‐conjugated ...
Lifen Chen, Lian Duan, Yidi Wang, Yasuteru Shigeta, Kowit Hengphasatporn, Linli Xu, Wai‐Yeung Wong   +6 more
wiley   +1 more source

Oxidation chemistry of d^0 organometallic complexes [PDF]

, 1990
Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demonstrate that even d^0 organometallic complexes exhibit a rich redox chemistry and present electrochemical, kinetics, and stereochemical studies that ...
Burk, Mark J., Tumas, William, Ward, Michael D., Wheeler, David R.   +3 more
core  

LMCT-driven electron relay unlocks alcohols as tunable reductants for nickel-catalyzed cross-electrophilic couplings

Nature Communications
Photoinduced electron transfer is fundamental to both biological and synthetic processes; however, modulating back electron transfer (BET) remains a formidable challenge in achieving more efficient photocatalytic transformations. In this work, we present
Shun Wang, Weidi Zeng, Qing An, Lingfei Duan, Zhiwei Zuo   +4 more
doaj   +1 more source

An NMR Database for Organic and Organometallic Compounds

Molecules
Databases of organic compounds are rooted in chemical formats, typically modeling chemical structures as simple graphical representations, which are easily readable by both humans and machines.
Stefan Kuhn, Markus Fischer, Herman Rull, Christophe Farès   +3 more
doaj   +1 more source