Cymantrene–Triazole "Click" Products: Structural Characterization and Electrochemical Properties [PDF]
We report the first known examples of triazole-derivatized cymantrene complexes (η5-[4-substituted triazol-1-yl]cyclopentadienyl)tricarbonylmanganese(I), obtained via a “click” chemical synthesis, bearing a phenyl, 3-aminophenyl, or 4-aminophenyl moiety ...
Abboud J.-L. M. +59 more
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Cyano-functionalized polyethylenes from ethylene/acrylamide copolymerization
Synthesizing functionalized polyethylenes via ethylene coordination copolymerization with fundamental low-cost vinyl polar monomers provides a very attractive approach.
Shu-Yang Yu +10 more
doaj +1 more source
Precise matching of reaction rate and electric potential of electrodes in paired electrolysis is challenging. Here, the authors develop paired-electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling of α-chloroesters and aryl ...
Dong Liu +6 more
doaj +1 more source
Hexagonal MASnI$_3$ exhibiting strong absorption of ultraviolet photons
MASnI$_3$, an organometallic halide, has great potential in the field of lead-free perovskite solar cells. Ultraviolet photons have been shown to generate deep trapping electronic defects in mesoporous TiO$_2$-based perovskite, affecting its performance ...
Ge, Yanfeng +7 more
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New Discoveries in the Realm of Metal–Metal Multiple Bonds:[η5-(C5Me5)Co2], the First Organometallic Multiple-Bond Complex without Bridging Ligands [PDF]
Double bond, yes or no? That is the poignant question in the case of the complex [Cp*CoCoCp*] prepared by J.J. Schneider et al. The Co-Co distance and the number of electrons suggest a double bond, while the H-1-NMR spectrum and the poor reactivity ...
Wachter, Joachim
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Tamoxifen-like metallocifens target thioredoxin system determining mitochondrial impairment leading to apoptosis in Jurkat cells [PDF]
Tamoxifen-like metallocifens (TLMs) of the group-8 metals (Fe, Ru, and Os) show strong anti-proliferative activity on cancer cell lines resistant to apoptosis, owing to their unique redox properties. In contrast, the thioredoxin system, which is involved
Alberto Bindoli +9 more
core +3 more sources
Organocatalytic synthetic route to esters and their application in hydrosilylation process
A facile esterification of α,β-unsaturated aldehydes with alcohols has been developed for the synthesis of esters by using bulky N-heterocyclic (NHC) carbene as a metal-free and eco-friendly organocatalyst.
Aleksandra Mermela +3 more
doaj +1 more source
Polyoxoniobates and Polyoxotantalates as Ligands—Revisited
This short review summarizes our contribution to the coordination chemistry of noble metals (organometallic fragments of Rh, Ir, Ru and hydroxo Pt(IV)) and polyoxocomplexes of niobium and tantalum.
Pavel A. Abramov +2 more
doaj +1 more source
Novel "green" catalysts for controlled ring-opening polymerization of lactide [PDF]
Syntéza polylaktidu (PLA) polymerací za otevření kruhu cyklického monomeru (ROP) může být uskutečněna různými způsoby. Literatura uvádí více než 100 katalytických systémů, jejichž pomocí lze polylaktid a jiné biodegradabilní alifatické polyestery získat.
Surman, František
core
Electronic correlations in organometallic complexes
We investigate an effective model for organometallic complexes (with potential uses in optoelectronic devices) via both exact diagonalisation and the configuration interaction singles (CIS) approximation.
A.C. Jacko +46 more
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