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Electron impact ionisation cross section for organoplatinum compounds
Molecular Physics, 2016ABSTRACTThis article reports electron impact ionisation cross sections for platinum-based drugs viz., cisplatin (H6N2Cl2Pt), carboplatin (C6H12N2O4Pt), oxaliplatin (C8H14N2O4Pt), nedaplatin (C2H8N2O3Pt) and satraplatin (C10H22ClN2O4Pt) complexes used in the cancer chemotherapy.
Dibyendu Mahato +2 more
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195Pt NMR of organoplatinum compounds
Journal of Organometallic Chemistry, 1985Abstract The 195 Pt chemical shifts of several organoplatinum compounds in solution have been determined. The δ( 195 Pt) values of the phosphine-Pt II and -Pt 0 compounds lie in separate ranges, and allow the metal-diene systems to be characterized either as metallacyclopentene or as η 2 -bonded diene. Although the two isomers of bis(η 3 -allyl)Pt
Reinhard Benn, Anna Rufinska
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EPR study of electron transfer and group transfer in organoplatinum(II) and (IV) compounds †
Journal of the Chemical Society Perkin Transactions II, 1997Chelate complexes between the 1,4-diazabuta-1,3-diene ligands RNCH–CHNR = R–DAB (R = alkyl, aryl) and the organoplatinum fragments PtMe2, PtMe4 and PtMes2 (Mes = mesityl) can be reversibly reduced to paramagnetic compounds, formulated as platinum(II) or (IV) species bound by radical anion ligands (R-DAB˙–).
Axel Klein, Wolfgang Kaim
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Dalton Transactions, 2012
The bioorganometallic platinum(II) compounds PtU6 and PtU5 were designed by the conjugation of the corresponding uracil derivative and the organoplatinum(II) compound [4-octyloxy-(C^N^N)PtCl]. The single crystal X-ray structure determination of PtU6 revealed the formation of the dimeric structure through intermolecular hydrogen bonds between the uracil
Toshiyuki Moriuchi +2 more
exaly +3 more sources
The bioorganometallic platinum(II) compounds PtU6 and PtU5 were designed by the conjugation of the corresponding uracil derivative and the organoplatinum(II) compound [4-octyloxy-(C^N^N)PtCl]. The single crystal X-ray structure determination of PtU6 revealed the formation of the dimeric structure through intermolecular hydrogen bonds between the uracil
Toshiyuki Moriuchi +2 more
exaly +3 more sources
Journal of the American Chemical Society, 1987
A series of ruthenium, Cp*(PMe/sub 3/)/sub 2/RuX (Cp* = eta/sup 5/-C/sub 5/Me/sub 5/), and platinum, (DPPE)MePtX (DPPE = Ph/sub 2/PCH/sub 2/CH/sub 2/PPh/sub 2/), compounds have been prepared. The equilibria L/sub n/M-X + H-Y in equilibrium L/sub n/M-Y + H-X (L/sub n/M = (DPPE)MePt or Cp*(PMe/sub 3/)/sub 2/Ru; X, Y = hydride, alkoxide, hydroxide, amide,
Henry E Bryndza, Wilson Tam
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A series of ruthenium, Cp*(PMe/sub 3/)/sub 2/RuX (Cp* = eta/sup 5/-C/sub 5/Me/sub 5/), and platinum, (DPPE)MePtX (DPPE = Ph/sub 2/PCH/sub 2/CH/sub 2/PPh/sub 2/), compounds have been prepared. The equilibria L/sub n/M-X + H-Y in equilibrium L/sub n/M-Y + H-X (L/sub n/M = (DPPE)MePt or Cp*(PMe/sub 3/)/sub 2/Ru; X, Y = hydride, alkoxide, hydroxide, amide,
Henry E Bryndza, Wilson Tam
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Accounts of Chemical Research, 2016
Over the past couple of decades, coordination-driven self-assembly has evolved as a broad multidisciplinary domain that not only covers the syntheses of aesthetically pleasing supramolecular architectures but also emerges as a method to form new optical materials, chemical sensors, theranostic agents, and compounds with light-harvesting and emissive ...
Manik Lal Saha +2 more
exaly +3 more sources
Over the past couple of decades, coordination-driven self-assembly has evolved as a broad multidisciplinary domain that not only covers the syntheses of aesthetically pleasing supramolecular architectures but also emerges as a method to form new optical materials, chemical sensors, theranostic agents, and compounds with light-harvesting and emissive ...
Manik Lal Saha +2 more
exaly +3 more sources
Journal of Organometallic Chemistry, 1998
Abstract During the course of our platinum cluster investigations [(CH3)3PtS(CH3)]4 (1) was synthesized according to Hall et al. (J.R. Hall, D.A. Hirons, G.A. Swile, J. Organomet. Chem. 174 (1979) 355) [1] from [(CH3)3Pt(H2O)3]2+SO42- and SCH3- ions in aqueous solution; [(CH3)3PtI]4·0.5CH3I (2) was obtained as the first logically derived product ...
E Herdtweck
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Abstract During the course of our platinum cluster investigations [(CH3)3PtS(CH3)]4 (1) was synthesized according to Hall et al. (J.R. Hall, D.A. Hirons, G.A. Swile, J. Organomet. Chem. 174 (1979) 355) [1] from [(CH3)3Pt(H2O)3]2+SO42- and SCH3- ions in aqueous solution; [(CH3)3PtI]4·0.5CH3I (2) was obtained as the first logically derived product ...
E Herdtweck
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Makromolekulare Chemie Macromolecular Symposia, 1988
AbstractThe complexation of appropriate organoplatinum compounds by water‐soluble polymers has the potential to provide a time‐release formulation which might afford a substantial reduction in the severity of side effects associated with use of organoplatinum antitumor agents. Both poly‐(N‐vinylpyrrolidone)(PVP) and poly(N‐vinyl‐5‐methyl‐2‐oxazolidone)(
B A Howell
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AbstractThe complexation of appropriate organoplatinum compounds by water‐soluble polymers has the potential to provide a time‐release formulation which might afford a substantial reduction in the severity of side effects associated with use of organoplatinum antitumor agents. Both poly‐(N‐vinylpyrrolidone)(PVP) and poly(N‐vinyl‐5‐methyl‐2‐oxazolidone)(
B A Howell
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Journal of Organometallic Chemistry, 1974
Abstract A novel reaction between both kinds of organomercurials and triphenyl-phosphine Pt 0 complexes is described, giving a useful route to σ-bonded organoplatinum(II) derivatives. Pd 0 complexes seem to follow a similar reaction pattern.
V I Sokolov, V V Bashilov, O A Reutov
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Abstract A novel reaction between both kinds of organomercurials and triphenyl-phosphine Pt 0 complexes is described, giving a useful route to σ-bonded organoplatinum(II) derivatives. Pd 0 complexes seem to follow a similar reaction pattern.
V I Sokolov, V V Bashilov, O A Reutov
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Carbon orbital hybridization in some organoplatinum compounds
Journal of the American Chemical Society, 1970Christopher David Cook, Kai Yan Wan
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