Results 221 to 230 of about 412,404 (295)

The Intricate Sabatier Optimality of Anion Electroreduction and Its Consequences for Nitrate Reduction

Angewandte Chemie, EarlyView.
The Sabatier principle and volcano plots declare that optimal electrocatalysis is found in the middle between strong and weak binding of key intermediates. However, it is shown here that during anion electroreduction, strong and weak binding are potential‐dependent concepts and volcanoes are mobile.
Mattia Salomone, Ioannis Katsounaros, Federico Calle‐Vallejo   +2 more
wiley   +2 more sources

Quantum squeezing amplification with a weak Kerr nonlinear oscillator. [PDF]

Nat Commun
Cai Y, Deng X, Zhang L, Ni Z, Mai J, Huang P, Zheng P, Hu L, Liu S, Xu Y, Yu D.   +10 more
europepmc   +1 more source

Highly Efficient Mechanochromic Thermally Activated Delayed Fluorescence in the Deep Red to Near‐Infrared in Copper(I) [2.2]Isoindolinophanyl‐Carbene Carbazolates

Angewandte Chemie, EarlyView.
Electrophilic [2.2]isoindolinophanyl‐based carbene iPC has been employed as charge‐transfer acceptor ligand in a series of [Cu(iPC)(carbazolate)], which show mechanochromism and environment‐dependent luminescence due to intermolecular C─‐H‐π interactions.
André M. T. Muthig, Sabyasachi Maity, Andreas Prüfer, Justin Krieger, Andrei Belyaev, Jan‐Benedikt Weiß, Sebastian Henke, Benjamin Hupp, Björn Ewald, Jens Pflaum, Andreas Steffen   +10 more
wiley   +2 more sources

A versatile large-scale coherent Ising machine from microwave to visible and telecom wavelength bands. [PDF]

Light Sci Appl
Zhang H, Li J, Zhu H.
europepmc   +1 more source

Two-Level Theory of Second-Order Nonlinear X-ray Response beyond the Electric-Dipole Approximation. [PDF]

J Phys Chem A
Mohan AV, Serrat C.
europepmc   +1 more source

Information theory and thermodynamic study of a 2D harmonic oscillator modified by inverse-square potential. [PDF]

Sci Rep
Hsu CY, Singh PK, Onate CA, Yusupov Y, Jumanazarov D, Mahariq I, Rajhi AA.   +6 more
europepmc   +1 more source

Closed-form spin-relativistic corrections from the Dirac equation enabling a modified Schrödinger solver. [PDF]

Sci Rep
Amaro MB, Nazeef, Dussech CJ, Qi C.
europepmc   +1 more source

Boron‐Doping of a Macrocyclic Tetrafuran Framework Unveils an Expanded Porphyrinoid With Switchable (Anti)Aromaticity and Conformational Dynamics

Angewandte Chemie, EarlyView.
We disclose a novel boron macrocycle derived from the sustainable furan building block. The boraporphyrinoid exhibits a global antiaromatic ring current and dynamic conformational flexibility. Twofold reduction induces a switch to strong global aromaticity, accompanied by stiffening of the porphyrinoid backbone.
Lukas Swoboda, Jonas Klopf, Jonas Bachmann, Ivo Krummenacher, Holger Braunschweig, Bernd Engels, Holger Helten   +6 more
wiley   +1 more source

Thermodynamic Operations and Entropy Considerations for a Ring-of-Charge Oscillator System. [PDF]

Entropy (Basel)
Cole DC.
europepmc   +1 more source

1,4‐Digermacyclopenta‐1,3‐diene: Continuous Cyclic σ*–π Delocalization Enables Aromatic Stabilization in a Heavy‐Element 4π System

Angewandte Chemie, EarlyView.
A five‐membered digermacycle exhibits an unusual 4π electron delocalization enabled by σ*(Ge–C)–π coupling within a nearly planar framework. Combined experimental and theoretical analyses reveal a continuous cyclic delocalization pathway, highlighting σ*–π interactions as a design principle for aromatic stabilization beyond classical π‐conjugated ...
Daichi Uchida, Hiroko Yamada, Yoshiyuki Mizuhata   +2 more
wiley   +1 more source