Results 71 to 80 of about 4,937 (261)
Nickel‐Catalyzed Reductive Cross‐Coupling of Xanthate Esters With Aryl and Alkenyl Iodides
Chemistry – A European Journal, EarlyView.A nickel‐catalyzed reductive cross‐coupling of xanthate esters and aryl/alkenyl iodides is reported without the need for separate activators for the xanthate esters. The reaction utilizes a relatively low catalyst loading. Diarylmethanes with a good functional group variety can thus be synthesized indirectly from the corresponding benzylic alcohols ...
Felix Vöhringer +4 more
wiley +1 more source
Hydrogen-bonding chain and dimer motifs in pyridinium and morpholinium hydrogen oxalate salts
Acta Crystallographica Section E: Crystallographic Communications, 2018 We present here three compounds consisting of pyridinium or morpholinium hydrogen oxalates, each displaying different hydrogen-bonding motifs, resulting in chains for 4-(dimethylamino)pyridinium hydrogen oxalate 0.22-hydrate, C7H11N2+·C2HO4−·0.22H2O (1),
David Z. T. Mulrooney +5 more
doaj +1 more source
Chemistry – A European Journal, EarlyView.Manganese oxides (MnOX) of different structures and with different Mn oxidation states exhibit significant variation in their reactivity toward the oxidation of allylic alcohols. Using two allylic alcohol model substrates, we demonstrate the relationship between activity and MnOX structure, Mn4+ content and incorporated secondary cations.
Erdogan Kasisari +6 more
wiley +1 more source
Pesquisa Agropecuária Brasileira, 1999 O objetivo deste trabalho foi promover uma avaliação nutricional da mistura protéica desengordurada, obtida do gergelim (Sesamum indicum L.), com a farinha extrudada do caupi (Vigna unguiculata L.
Geraldo Arraes Maia +4 more
doaj
Fibrous osteodystrophy in a Lavradeira filly associated with Brachiaria humidicola ingestion
Agro@mbiente On-line, 2019 Fibrous osteodystrophy in horses is due to low calcium ingestion, high phosphorus ingestion, high oxalate ingestion, or a combination of these. Tropical forages usually have high levels of oxalates, which prevents calcium absorption and results in ...
Fernanda Carlini Cunha Santos
doaj +1 more source
Chemistry – A European Journal, EarlyView.This work describes the first example of a thermally stable α‐SF5 organometallic reagent, which allows for extensive downstream functionalization by allylation and acylation reactions under copper catalysis, as well as palladium‐catalyzed Negishi‐type cross‐coupling conditions up to 96% yield. In silico analysis shines initial light on the requirements
Lujie Xu, David Rombach
wiley +1 more source
Experimental methods in chemical engineering: Temperature‐programmed oxidation—TPO
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Temperature‐programmed oxidation (TPO) probes the oxidative capacity and redox properties of solid materials—catalysts, metal oxides, perovskites, and carbonaceous deposits. It identifies coke type, distribution, and reactivity. TPO instruments pass an oxidizing gas (diluted O2$$ {\mathrm{O}}_2 $$, air, or less commonly N2O$$ {\mathrm{N}}_2 ...
Gholamreza Roohollahi +7 more
wiley +1 more source
Nature Communications, 2018 Converting alkynes into alkenes with high stereoselectivity via two consecutive C-C bond forming steps is a desirable process, yet very challenging. Here, the authors describe a dual photoredox-nickel catalytic system for the regio- and syn-selective ...
Lei Guo +4 more
doaj +1 more source
CleanMat, EarlyView.To develop recycling processes for lithium‐ion batteries, wastewater treatment for the removal of organic compounds originating from the electrolyte was investigated using electro‐oxidation and ozonation. Based on the results, this paper proposes a process which combines these two methods to remove alcohols derived from the solvent and additives ...
Takumi Yasuda, Tetsuya Uda
wiley +1 more source