Bis(oxalato)borate Salts as Safe and Fluorine-Free Alternatives to Conventional Supporting Electrolytes for Organic Electrosynthesis. [PDF]
Lithium bis(oxalato)borate (LiBOB) was established as a new tool in the repertoire of the synthetic organic electrochemist. As a sustainable alternative to conventional supporting electrolytes, LiBOB shows high stability and ionic conductivity while in test reactions, product yields are comparable to standard electrolyte systems.
Scherkus A, He Z, Francke R.
europepmc +2 more sources
Development of Low Fluorinated, Sustainable, and Recyclable Electrolytes Based on γ-Valerolactone for High-Performance Sodium-Ion Batteries. [PDF]
ABSTRACT This study introduces a dual salt novel electrolyte for sodium‐ion batteries (SIBs), consisting of sodium difluoro(oxalato)borate (NaDFOB) and sodium bis(fluorosulfonyl)imide (NaFSI) salts dissolved in the bio‐based γ‐valerolactone (GVL) solvent.
Lu Y +8 more
europepmc +2 more sources
Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate [PDF]
Six new BEDT-TTF salts with tris(oxalato)gallate or -iridate anions including two new superconductors β′′-(BEDT-TTF)4[(H3O)Ga(C2O4)3]·guest (bromobenzene or iodobenzene) and a novel 5 : 1 metal–insulator β′′-(BEDT-TTF)5Ir(C2O4)3 ethanol.
Toby J. Blundell +12 more
openaire +2 more sources
An Oxalate-Bridged Copper(II) Complex Combining Monodentate Benzoate, 2,2'-bipyridine and Aqua Ligands:Synthesis, Crystal Structure and Investigation of Magnetic Properties [PDF]
A dinuclear copper(II) complex of formula [{Cu(bipy)(bzt)(OH2)}2(μ-ox)] (1) (where bipy = 2,2'-bipyridine, bzt = benzoate and ox = oxalate) was synthesised and characterised by diffractometric (powder and single-crystal XRD) and thermogravimetric (TG/DTG)
Briganti, Matteo +7 more
core +1 more source
Chirality in charge-transfer salts of BEDT-TTF of tris(oxalato)chromate(III) [PDF]
Crystallisation from chiral electrolyte (R)-(−)-carvone has produced three new chiral semiconducting salts of BEDT-TTF from racemic anion tri(oxalato)chromate(III)
Abboud +55 more
core +1 more source
Durante 150 dias, 12 potras Quarto-de-Milha de 1 ano de idade permaneceram exclusivamente em pastagem de Brachiaria humidicola, num experimento inteiramente casualizado, com três tratamentos, nível 0 (recomendação do NRC, 1989); nível 50 (50% a mais do ...
José Nicolau Prospero Puoli Filho +2 more
doaj +1 more source
Peter Day’s research group reported the first molecular superconductor containing paramagnetic metal ions in 1995, β″-(BEDT-TTF)4(H3O)Fe(C2O4)3·C6H5CN. Subsequent research has produced a multitude of BEDT-TTF-tris(oxalato)metallate salts with a variety ...
Toby James Blundell +6 more
doaj +1 more source
A formação de P não-lábil a partir de formas lábeis, adsorvidas aos oxihidróxidos de Fe e Al, é razão para o baixo efeito residual da fertilização fosfatada em solos tropicais.
Iván Ernesto Fernández R. +3 more
doaj +1 more source
Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(II) organometallics [PDF]
Dinuclear metal complexes have emerged as a promising class of biologically active compounds which possess unique anticancer activity. Here, we describe a novel series of arene-linked dinuclear organometallic Ru(II) complexes, where the relative ...
Dyson, Paul J. +3 more
core +2 more sources
Química e gênese de solos desenvolvidos sob vegetação de restinga no estado de São Paulo
As áreas arenosas e de solos pobres com vegetação característica das planícies costeiras brasileiras são genericamente denominadas de restinga. Os solos desses ambientes foram muito pouco estudados. Para este estudo, selecionaram-se áreas de restinga dos
Maurício Rizzato Coelho +4 more
doaj +1 more source

