Results 1 to 4 of about 8 (4)
NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral. The anions behave as monochelating ligands.
GORGUI AWA SECK +2 more
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AbstractDie gemäß einer 1:1‐St‐öchiometrie (Gleichung A) ablaufenden Oxidationsreaktionen von [Ru(NH3 )6 ]2 (I) und [Ru(NH3)5 OH, 12+ (II) mit [Co(NH3)4 (C204)? (III) und [Co(NH3 )5 (HC,O4)]′ (IV) werden bei einer Ionenstärke von 0.20 mol dm′3 (LiCl) in Abhängigkeit von der HCl‐Konzentration untersucht.
J. F. OJO, A. O. OJUDUN, O. A. OLUBUYIDE
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The oxidations of [Ru(NH3)6]2+ and [Ru(NH3)5(OH2)]2+ by [Co(NH3)4(C2O4)]+ and [Co(NH3)5(HC2O4)]2+ have been investigated at an ionic strength of 0.20 mol dm–3(LiCl) at various acid (HCl) concentrations. The oxidation of both ruthenium(II) species by [Co(NH3)4(C2O4)]+ is acid-independent whereas that by [Co(NH3)5(HC2O4)]2+ is acid-inhibited.
J. Folorunso Ojo +2 more
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