Results 21 to 30 of about 558,651 (312)

Thermal oxidation kinetics of additive free polyamide 6-6 [PDF]

open access: yes, 2013
Thermal aging of an additive free PA 6-6 has been elucidated at 90, 100, 120, 140, 150 and 160 C in airventiled ovens by Fourier transform infrared spectrophotometry, viscosimetry in molten state and uniaxial tensile testing.
BEN HASSINE, Mouna   +3 more
core   +1 more source

Active catalyst construction for CO2 recycling via catalytic synthesis of N-doped carbon on supported Cu

open access: yesNature Communications, 2019
Bridging homogeneous and heterogeneous catalysis is a long-term pursuit in the field of catalysis. Here, the authors present results on integration of nano- and molecular catalysis via catalytic synthesis of nitrogen doped carbon layers on AlOx supported
Yajuan Wu   +5 more
doaj   +1 more source

Oxidation of cellulose in pressurized carbon dioxide [PDF]

open access: yes, 2009
This work presents first results upon oxidation of type II cellulose by nitrogen dioxide dissolved in carbon dioxide at high pressure. This reaction leads to oxidized cellulose, a natural-based bioresorbable fabric used for biomedical applications.
Montanari, Suzelei   +4 more
core   +1 more source

Iodine-catalyzed diazo activation to access radical reactivity

open access: yesNature Communications, 2018
Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under ...
Pan Li   +5 more
doaj   +1 more source

Effect of doping TiO2 with alkaline-earth metal ions on its photocatalytic activity [PDF]

open access: yesJournal of the Serbian Chemical Society, 2007
TiO2 photocatalysts doped with alkaline-earth metal ions were prepared by the impregnation and coprecipitation methods. The sample were characterized by XRD, XPS and IR spectroscopy.
Li Yuexiang   +4 more
doaj   +1 more source

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

open access: yesBeilstein Journal of Nanotechnology, 2022
In this study, we present theoretical X-ray absorption near-edge structure (XANES) spectra at the K-edge of oxygen in zirconia containing Ni dopant atoms and O vacancies at varying concentrations.
Dick Hartmann Douma   +6 more
doaj   +1 more source

The dn Number in Transition Metal Chemistry: Its Utility and Limitations

open access: yesChemistry, 2023
The dn number or configuration is a very useful parameter in transition metal chemistry because it conveys information about the expected properties of a d-block metal complex, including its shape, magnetism, thermodynamic stability, kinetic lability ...
Nicholas C. Norman, Paul G. Pringle
doaj   +1 more source

Chemical State of Complex Uranium Oxides [PDF]

open access: yesPhysical Review Letters, 2013
We report here the first direct observation of U(V) in uranium binary oxides and analyze the gradual conversion of the U oxidation state in the mixed uranium systems. Our finding clarifies previous contradicting results and provides important input for the geological disposal of spent fuel, recycling applications and chemistry of uranium species.
Kvashnina, K. O.   +3 more
openaire   +3 more sources

The effect of oxidation state on the viscosity of melts in the system Na2O-FeO-Fe2O3-SiO2 [PDF]

open access: yes, 1987
The viscosities of two melts in the system Na2O-FeO-Fe2O3-SiO2 have been measured as a function of oxidation state. The experiments were conducted by concentric-cylinder viscometry, on melts equilibrated with gas mixtures in a vertical tube, gas-mixing ...
Virgo, David, Dingwell, Donald B.
core   +1 more source

Polyoxometalate-Based Catalysts for CO2 Conversion

open access: yesMolecules, 2019
Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of ...
Yanwei Cao   +3 more
doaj   +1 more source

Home - About - Disclaimer - Privacy