Results 21 to 30 of about 18,231,952 (248)

Iodine-catalyzed diazo activation to access radical reactivity

open access: yesNature Communications, 2018
Radical reactivity of diazo compounds, useful organic building blocks, is yet underexplored. Here, the authors report an iodine-catalyzed radical activation of diazo compounds affording a variety of substituted cyclopropanes, pyrroles and epoxides under ...
Pan Li   +5 more
doaj   +1 more source

Effect of doping TiO2 with alkaline-earth metal ions on its photocatalytic activity [PDF]

open access: yesJournal of the Serbian Chemical Society, 2007
TiO2 photocatalysts doped with alkaline-earth metal ions were prepared by the impregnation and coprecipitation methods. The sample were characterized by XRD, XPS and IR spectroscopy.
Li Yuexiang   +4 more
doaj   +1 more source

Polyoxometalate-Based Catalysts for CO2 Conversion

open access: yesMolecules, 2019
Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of ...
Yanwei Cao   +3 more
doaj   +1 more source

Impact of Physico-Chemical Properties of Cellulose Nanocrystal/Silver Nanoparticle Hybrid Suspensions on Their Biocidal and Toxicological Effects

open access: yesNanomaterials, 2021
There is a demand for nanoparticles that are environmentally acceptable, but simultaneously efficient and low cost. We prepared silver nanoparticles (AgNPs) grafted on a native bio-based substrate (cellulose nanocrystals, CNCs) with high biocidal ...
Dafne Musino   +8 more
doaj   +1 more source

Oxidation kinetics of a Ni-Cu based cermet at high temperature [PDF]

open access: yes, 2013
The oxidation kinetics of a cermet composed of Ni–Cu alloy and nickel ferrite was studied by thermogravimetry at 960 °C under oxygen in the range 0.5–77 kPa. After an initial mass increase up to 15 g/m2 due to oxidation of surface metallic particles, the
Palau, Patrice   +14 more
core   +1 more source

Graphitic phosphorus coordinated single Fe atoms for hydrogenative transformations

open access: yesNature Communications, 2020
Phosphorus ligands have been extensively used in metal complexes for homogeneous catalysis. Here, the authors broaden this scope to heterogeneous catalysis by preparing a P-coordinated Fe single atom catalyst with excellent catalytic performance in ...
Xiangdong Long   +8 more
doaj   +1 more source

Thermal oxidation kinetics of additive free polyamide 6-6 [PDF]

open access: yes, 2013
Thermal aging of an additive free PA 6-6 has been elucidated at 90, 100, 120, 140, 150 and 160 C in airventiled ovens by Fourier transform infrared spectrophotometry, viscosimetry in molten state and uniaxial tensile testing.
BEN HASSINE, Mouna   +3 more
core   +1 more source

Co-oxidation kinetic model for the thermal oxidation of polyethylene-unsaturated substrate systems [PDF]

open access: yes, 2013
The thermal oxidation of polyethylene (PE) impregnated by the methyl esters of unsaturated fatty acids (UFEs) was studied using chemiluminescence, and infra-red spectrophotometry.
RYCHLÝ, Jozef   +3 more
core   +1 more source

Synthesis of a molecularly defined single-active site heterogeneous catalyst for selective oxidation of N-heterocycles

open access: yesNature Communications, 2018
Synthesis of molecularly defined single-active site catalytic materials is the key to bridging the gap between homogeneous and heterogeneous catalysis.
Yujing Zhang   +6 more
doaj   +1 more source

Theoretical investigations of oxygen vacancy effects in nickel-doped zirconia from ab initio XANES spectroscopy at the oxygen K-edge

open access: yesBeilstein Journal of Nanotechnology, 2022
In this study, we present theoretical X-ray absorption near-edge structure (XANES) spectra at the K-edge of oxygen in zirconia containing Ni dopant atoms and O vacancies at varying concentrations.
Dick Hartmann Douma   +6 more
doaj   +1 more source

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