Results 51 to 60 of about 13,910,228 (354)

Synthesis of a molecularly defined single-active site heterogeneous catalyst for selective oxidation of N-heterocycles

open access: yesNature Communications, 2018
Synthesis of molecularly defined single-active site catalytic materials is the key to bridging the gap between homogeneous and heterogeneous catalysis.
Yujing Zhang   +6 more
doaj   +1 more source

Control of oxidation and spin state in a single-molecule junction [PDF]

open access: yes, 2018
The oxidation and spin state of a metal–organic molecule determine its chemical reactivity and magnetic properties. Here, we demonstrate the reversible control of the oxidation and spin state in a single Fe porphyrin molecule in the force field of the ...
Braun, Lukas   +6 more
core   +3 more sources

Synthesis and catalytic performance of CeOCl in Deacon reaction [PDF]

open access: yes, 2013
Surface chlorinated CeO2 is an efficient material for HCl oxidation, which raises the question whether an oxychloride phase could be also active in the same reaction.
Farra, R.   +5 more
core   +1 more source

Characterization of the zircon Ce anomaly for estimation of oxidation state of magmas: a revised Ce/Ce* method

open access: yesMineralogy and Petrology, 2019
As a proxy of magmatic oxidation state, the accurate characterization of the Ce anomaly of zircon is of great significance since it can give important information for provenance studies of rocks as well as for exploration of intrusion-related mineral ...
Shihua Zhong   +3 more
semanticscholar   +1 more source

The para-substituent effect and pH-dependence of the organometallic Baeyer–Villiger oxidation of rhenium–carbon bonds [PDF]

open access: yes, 2012
We studied the Baeyer–Villiger (BV) type oxidation of phenylrhenium trioxide (PTO) by H2O2 in the aqueous phase using Quantum Mechanics (density functional theory with the M06 functional) focusing on how the solution pH and the para-substituent affect ...
Bischof, Steven M.   +5 more
core   +1 more source

Mapping the evolution of mitochondrial complex I through structural variation

open access: yesFEBS Letters, EarlyView.
Respiratory complex I (CI) is crucial for bioenergetic metabolism in many prokaryotes and eukaryotes. It is composed of a conserved set of core subunits and additional accessory subunits that vary depending on the organism. Here, we categorize CI subunits from available structures to map the evolution of CI across eukaryotes. Respiratory complex I (CI)
Dong‐Woo Shin   +2 more
wiley   +1 more source

Probing Active Sites and Reaction Intermediates of Electrocatalysis Through Confocal Near-Infrared Photoluminescence Spectroscopy: A Perspective

open access: yesFrontiers in Chemistry, 2020
Electrocatalytic reactions such as oxygen evolution (OER) and oxygen reduction reactions (ORR) are one of the most complex heterogeneous charge transfer processes because of the involvement of multiple proton-coupled-electron transfer steps over a narrow
Vidhya Chakrapani, Vidhya Chakrapani
doaj   +1 more source

Conceptual Exchanges for Understanding Free-Living and Host-Associated Microbiomes

open access: yesmSystems, 2022
Whether a microbe is free-living or associated with a host from across the tree of life, its existence depends on a limited number of elements and electron donors and acceptors.
Catherine A. Pfister   +8 more
doaj   +1 more source

Molecular Complex of Tb in the +4 Oxidation State.

open access: yesJournal of the American Chemical Society, 2019
Lanthanides (Ln) usually occur in the +3, or more recently the +2, oxidation states. The only example of an isolated molecular Ln4+ so far remains Ce4+.
Chad T. Palumbo   +3 more
semanticscholar   +1 more source

Spatiotemporal and quantitative analyses of phosphoinositides – fluorescent probe—and mass spectrometry‐based approaches

open access: yesFEBS Letters, EarlyView.
Fluorescent probes allow dynamic visualization of phosphoinositides in living cells (left), whereas mass spectrometry provides high‐sensitivity, isomer‐resolved quantitation (right). Their synergistic use captures complementary aspects of lipid signaling. This review illustrates how these approaches reveal the spatiotemporal regulation and quantitative
Hiroaki Kajiho   +3 more
wiley   +1 more source

Home - About - Disclaimer - Privacy