Defect structures and migration mechanisms in oxide pyrochlores [PDF]
Using computer simulation techniques the defect structure and oxygen ion migration mechanism of oxide pyrochlores (eg. Gd2Zr2O7) was investigated in order to explain the decreased activation enthalpy for oxygen ion conductivity as a function of order ...
Burggraaf, A.J. +3 more
core +3 more sources
Oxide Ion Conductivity of Mechanically produced Calcia Stabilised Zirconia for Oxygen Sensing Applications [PDF]
Cryo-milling was used to make calcia stabilized zirconia (CSZ) powders with 9 mol%, 12 mol%, and 15 mol% of calcia. Powder X-ray diffraction was done to examine the phase growth in prepared powders over the course of 80h of mechanical alloying (MA) in ...
M. Kannan, Satyendra Singh, R.R. Prasad
doaj +1 more source
Coulomb explosion sputtering of selectively oxidized Si [PDF]
We have studied multiply charged Arq+ ion induced potential sputtering of a unique system comprising of coexisting Silicon and Silicon oxide surfaces. Such surfaces are produced by oblique angle oxygen ion bombardment on Si(100), where ripple structures ...
A Chakrabarti +8 more
core +1 more source
The effect of dual substitution of Na and Al on ionic conductivity of Na0.5Bi0.5TiO3 ceramics
The Na and Al dual substitution Na0.5Bi0.5TiO3 samples were synthesized by the conventional solid-state reaction method. The oxygen ion conductivity and migration in the Na0.54Bi0.46Ti1−xAlxO2.96−x/2 (x = 0.02, 0.04, 0.06 and 0.08) samples were ...
W.G. Wang, X.Y. Li, T. Liu, G.L. Hao
doaj +1 more source
Synthesis, structure and electrical properties of Li+-doped pyrochlore Gd2Zr2O7
The pyrochlore Gd1.55Li0.45Zr2O6.55 was prepared by the solution and solid-state methods. The introduction of lithium in the Gd-sublattice led to decrease in the lattice parameter a = 10.4830(8) Å in comparison with Gd2Zr2O7 (a =10.5346(2) Å). Monitoring
Irina A. Anokhina +6 more
doaj +1 more source
Electric properties of oxyfluorides Ba2In2O 5-0.5x F x with brownmillerite structure [PDF]
Synthesis of fluoro-substituted substances based on brownmillerite Ba 2In2O5 is carried out. The width of the homogeneity region of the Ba2In2O5-0.5x F x (0 < x ≤ 0.25) solid solution was established using X-ray analysis.
Animitsa, I. E. +2 more
core +1 more source
Electrical and catalytic properties of some oxides with the fluorite or pyrochlore structure: Part 2: Catalytic oxidation of carbon monoxide [PDF]
The catalytic properties of mixed oxides with the fluorite or pyrochlore structure were investigated using CO oxidation. The presence of ions with a variable valence state, the size of the ions and especially the extent of pyrochlore ordering affect ...
Bosch, H. +6 more
core +11 more sources
The impressive ionic conductivity and tunable conduction behaviors have made the ceria-carbonate composite an attractive electrolyte for low temperature ceramic fuel cells. However, the conduction mechanism is not yet well studied.
Liangdong Fan +5 more
doaj +1 more source
Composite electrolyte used for low temperature SOFCs to work at 390°C
Summary: A combination of yttria stabilized zirconia (YSZ) and Ba(NO3)2 commercial powders was used as electrolytes in the construction of symmetrical SOFC.
Yu Liu +4 more
doaj +1 more source
Mixed-conducting LSC/CGO and Ag/CGO composites for passive oxygen separation membranes [PDF]
Dense ceramic oxygen separation membranes can pass oxygen perm-selectively at elevated temperature and have potential for improving the performance and reducing the cost of several industrial processes: such as the conversion of natural gas to syngas,
Seeharaj, Panpailin, Seeharaj, Panpailin
core +1 more source

