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Armalcolite stability as a function of pressure and oxygen fugacity
Geochimica et Cosmochimica Acta, 1977High-pressure experiments in a piston-cylinder apparatus with silver-palladium containers were conducted to study the stability of synthetic armalcolite, (Fe,Mg)Ti2O5, as a function of pressures up to 15 kbar at 1000, 1100, and 1200 C. Three armalcolite compositions were used, each with an initial Fe/(Fe + Mg) ratio of 0.5.
John J Friel, R.Ian Harker, Gene C Ulmer
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Zircon as a recorder of the oxygen fugacity of magmas
2012Zircon (ZrSiO4) is a durable mineral found in most igneous rocks; it is highly retentive of the trace element concentrations it acquires at crystallisation, and its high initial concentrations of U and Th relative to Pb make it the most important mineral for radiometric dating.
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Sodic Amphiboles as Oxygen Fugacity Indicators in Metamorphism
The Journal of Geology, 1980Analyses of sodic amphiboles from a blueschist metamorphic terrain of constant grade in the Tavsanli area, Northwest Turkey, show that practically the whole range of sodic amphibole compositions is stable in the glaucophane-lawsonite facies. By analysing sodic amphiboles coexisting with magnetite and hematite, it has proved possible to plot for a ...
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Measurement and control of oxygen fugacity during annealing
Review of Scientific Instruments, 1984We describe a simple analog electronic circuit to measure the voltages of a thermocouple and solid electrolyte sensor and calculate and diplay the temperature and log fO2. This circuit monitors conditions in a simple annealing system where the oxygen atmosphere is controlled by continuous flow of a gas buffer.
John P. Shepherd, Charles J. Sandberg
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Oxygen fugacity controls in the Earth's upper mantle
Nature, 1990DESPITE significant progress in recent years1–3, there is still considerable debate surrounding the oxygen fugacity (fo2) of the Earth's upper mantle and the chemical reactions that buffer it. Electrochemical measurements1,3 give heterogeneous oxidation states, with one group near the fayalite–magnetite–quartz (FMQ), and the other near the iron-wustite
C. Ballhaus, R. F. Berry, D. H. Green
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Kaersutitic and Ti-pargasitic amphiboles and oxygen fugacity
2008Since long time kaersutite and Ti-pargasite were studied because they are retained to be useful for the estimation of fO2 and fH2 conditions of their hosting rocks (especially for mantle derived rocks and nodules). These amphiboles have currently low hydrogen (even close to 0) content than the classical 2 a.p.f.u..
Iezzi G +3 more
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Equilibrium oxygen fugacity in zinc-titanium ferrites of ideal oxygen stoichiometry
Materials Research Bulletin, 1988Abstract A thermodynamic analysis is provided to specify the oxygen equilibrium pressures in the system Znx Tiy Fe3−x−yO4 for the special case of the ideal oxygen stoichiometry O ( Zn + Ti + Fe ) , 4 3 . The principal features of the results are briefly discussed.
P. Wang, J.M. Honig
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The oxygen fugacity within carbonated eclogites
2011The subduction of carbon back into the mantle is an important natural form of carbon sequestration. Eclogitic nodules and CO2-rich metasomatic agents show evidence for the passage of carbon and carbonate (solid or melts) in the mantle. Further, diamonds from kimberlites occur in eclogite xenoliths more frequently than in peridotite xenoliths but the ...
STAGNO, VINCENZO, Frost, DJ, McCammon CA
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Records of Archean mantle oxygen fugacity
Goldschmidt2023 abstracts, 2023Elizabeth Cottrell +5 more
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The effect of hydrogen, oxygen, and water fugacity on oxygen diffusion in alkali feldspar
Geochimica et Cosmochimica Acta, 1990Abstract Oxygen self-diffusion in adularia and albite single crystals was studied hydrothermally at 650°C from 5 to 1500 MPa confining pressure using a combination of hydrogen/oxygen buffers, a hydrogen ion buffer, and variable mole fractions of water (dilution with CO2).
John R. Farver, Richard A. Yund
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