Results 101 to 110 of about 11,148 (232)

Influence of Carboxylate Ligand Variation on Structure, Magnetic Exchange, and Magnetocaloric Performance in Hexanuclear Gd(III) Complexes

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Hexanuclear cyclic Gd(III) coordination compounds are promising candidates for magnetic and magnetocaloric applications, yet systematic series remain rare due to synthetic challenges. We report the synthesis and characterization of five new complexes with the general formula [Gd(H3bt)(carboxylate)]6, employing four different carboxylate ...
Ondřej František Fellner   +7 more
wiley   +1 more source

Enzymatic Prenylation of Proteins and Peptides: From Cysteine S‐Prenylation to Tryptophan‐Selective Biocatalysis

open access: yesChemistry – A European Journal, EarlyView.
This review highlights biocatalytic prenylation as a versatile strategy for tailoring the functional properties of peptides and proteins. By comparing branched isoprenoids with linear lipids, we illustrate how specific prenyl architectures modulate the behaviors of lipidated proteins within membrane environments.
Daisuke Fujinami   +2 more
wiley   +1 more source

Exploring Tradeoffs in Syngas Production With Solid‐Oxide Electrolysis via Multi‐Objective Optimization

open access: yesChemie Ingenieur Technik, EarlyView.
This work applies multi‐objective optimization to investigate trade‐offs between different objectives in syngas production with solid‐oxide cell co‐electrolysis. Two system designs are investigated. By systematically exploring tradeoffs between different objectives, insights, and comparisons of the operation of these designs are achieved.
Gbenga Jerome   +6 more
wiley   +1 more source

Energy Landscapes in Chemical Reactions and Transport

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley   +1 more source

Transient Change of Io's Neutral Oxygen Cloud andPlasma Torus Observed by Hisaki

open access: yesTransient Change of Io's Neutral Oxygen Cloud andPlasma Torus Observed by Hisaki
著者人数: 11名 Accepted: 2019-11-14 資料番号 ...
openaire  

Heat Load Mitigation Studies in the W7‐X Stellarator Experiment

open access: yesContributions to Plasma Physics, EarlyView.
ABSTRACT During the experiments at the stellarator Wendelstein 7‐X (W7‐X) with fully water‐cooled plasma‐facing components (PFC), including carbon‐fiber composite (CFC) divertor targets with a thermal load capability of 10 MW/m2, high performance was achieved.
Dirk Naujoks   +11 more
wiley   +1 more source

Ultra‐High Strength and Environmentally Stable Fluorinated Solid‐State Ion‐Conductive Elastomers with Folding‐Paper‐Structured Triboelectric Nanogenerators for Wave Energy Harvesting

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this work, a polyurethane‐based fluorinated SICEs with excellent mechanical properties (7.35 MPa and 61.4 MJ m−3), conductivity (4.2 × 10−4 S cm−1), and harsh environmental resistance were prepared by a “three birds with one stone” strategy that combines multiple interactions with fluorine effects. The paper‐folding TENG is capable of harvesting not
Zequan Li   +9 more
wiley   +1 more source

Fish Scales: A Multifunctional Biomaterial from Nature

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Fish scales demonstrate nature's solution to impact protection through overlapping multilayered architecture. This biological design combines mineralized surfaces with collagen networks to achieve both flexibility and fracture resistance. The structural principles inspire advanced protective materials and biomedical implants, where damage tolerance ...
Liyao Dong, Xiaojie Sun, Xiguang Chen
wiley   +1 more source

Mechanistic Paths for the Gold(I)‐Catalyzed Heteroannulation of Salicylic Amides With Apolar Alkynes Explored With Density Functional Theory Calculations

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A manifold of catalytic reaction paths can operate in the Au(I)‐catalyzed heteroannulation of salicylic amides and alkynes. However, a subtle initial nucleophilic advantage of N versus O and a kinetic bottleneck at an advanced stage of the mechanistic machinery seems to suffice for the reaction to run on a single path and with exquisite selectivity. We
Ioannis Stylianakis   +3 more
wiley   +1 more source

Antibacterial Hydrogel Dressing With Ca2+‐Dependent Hyaluronidase Responsiveness for Accelerating Wound Healing via On‐Demand Release of AIE Photosensitizers

open access: yesExploration, EarlyView.
This study innovates a Ca2+‐responsive hydrogel dressing that releases AIE photosensitizers on‐demand. Low Ca2+ enhances bacterial hyaluronidase (HAase) activity, degrading hyaluronic acid dressing to trigger antibacterial ROS release, while high Ca2+ inhibits HAase, preventing overdosing.
Rongwei Cui   +12 more
wiley   +1 more source

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