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Selective toluene methylation to p-xylene: current status & future perspective

Catalysis reviews, 2022
Industrially, petroleum naphtha reforming and steam cracking are two major multistep and energy-intensive sources for p-xylene production. Additionally, p-xylene is also produced by selective toluene disproportionation, heavy (C9) aromatics trans ...
L. Kumar   +3 more
semanticscholar   +1 more source

Record-setting selectivity for p-xylene by an intrinsically porous 0D metallocycle.

Journal of the American Chemical Society, 2020
In its crystalline state a dinuclear Cu-based metallocycle discrimi-nates between the three isomers of xylene with liquid-phase selec-tivity in the order p-xylene  m-xylene  o-xylene. This selectiv-ity holds over a wide concentration range, with para-
Marike du Plessis   +2 more
semanticscholar   +1 more source

Poly(p-xylene disulfide) and poly(p-xylene tetrasulfide): synthesis, cure and investigation of mechanical and thermophysical properties

, 2020
In this work, two polysulfide polymers were synthesized using aromatic organic monomer (α,α′-dichloro-p-xylene) and sodium disulfide (Na2S2) and sodium tetrasulfide (Na2S4) aqueous monomers. Then, the curing process of the polymers was carried out at 170°
M. Sheydaei   +4 more
semanticscholar   +1 more source

The Origin of p-Xylene Selectivity in a DABCO Pillar-Layered Metal-Organic Framework: a Combined Experimental and Computational Investigation.

ACS Applied Materials and Interfaces, 2019
Separation of p-xylene (pX) from xylene isomers is an important and challenging issue due to the similar physical properties between the molecules. In this study, we found that 1,4-diazabicyclo[2.2.2]octane (DABCO) has a selective interaction with pX and
Seung-Ik Kim   +3 more
semanticscholar   +1 more source

Ultrafast, Highly Sensitive, and Selective Detection of p-Xylene at Room Temperature by Peptide-Hydrogel-Based Composite Material

ACS Applied Polymer Materials, 2019
A peptide/carbon dot (CD) composite xerogel is used as a selective p-xylene VOC (volatile organic compound) sensor. The fiber formation by the peptide allows us to attain a semiconducting property, whereas the presence of the CD amplifies the sensitivity.
Nilotpal Singha   +6 more
semanticscholar   +1 more source

Nanoporous ZSM-5 Crystals Coated with Silicalite-1 for Enhanced p-Xylene Separation

ACS Applied Nano Materials, 2019
The growth of a silicalite-1 coating on ZSM-5 zeolite crystals is one of the surface modification methods allowing to improve its catalytic p-xylene selectivity.
M. Miyamoto   +7 more
semanticscholar   +1 more source

Selective conversion of furans to p ‐xylene with surface‐modified zeolites

Journal of Chemical Technology & Biotechnology, 2019
BACKGROUND: Owing to the growing consumption of oil and the negative environmental impacts, the production of p‐xylene (PX) from renewable biomass has gained significant attention recently.
Lijuan Zhu   +5 more
semanticscholar   +1 more source

Binary Adsorption Equilibrium and Breakthrough of n-Butyl Acetate and p-Xylene on Granular Activated Carbon

Industrial & Engineering Chemistry Research, 2019
Compared with abatement methods (regenerative thermal oxidizer, regenerative catalytic oxidizer, etc.), the adsorption–desorption combined method has been considered as a sustainable way to treat and recover volatile organic compounds (VOCs) from off ...
Hong Sui   +5 more
semanticscholar   +1 more source

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