Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z‐Type Ligands
Rare examples of alkyl bismuth cations [BiR2(SbF6)] are presented, including cyclopropyl ligands and a bismacyclic structure. The bismuth‐centered Lewis acids act as Z‐type ligands toward the electron‐rich platinum atom in [Pt(PCy3)2], generating a set of metal‐only Lewis pairs. The structural and spectroscopic properties of these rare types of bismuth
Johannes Schwarzmann +7 more
wiley +1 more source
Exercise rejuvenates bone marrow mesenchymal stem cells associated with the inhibition of inflammatory factors and senescence-related factors. [PDF]
Dong XJ +5 more
europepmc +1 more source
The synthesis of a bench‐stable trifluoromethylthiolate‐substituted phosphazenium salt is reported. Reaction of bis(trifluoromethyl)disulfide with the EtP4 phosphazene base furnishes this salt in quantitative yield. The compound features a unique trifluoromethylthiolate‐iminium motif and allows for functionalization of both trifluoromethylthiolate ...
Lukas Hartmann +6 more
wiley +1 more source
Prenatal Edible Bird's Nest Supplementation Attenuates Offspring Skin Pigmentation via Dual Inhibition of CREB and ERK Signaling to Downregulate MITF-TYR Axis. [PDF]
Zhang W +8 more
europepmc +1 more source
Variable Temperature Studies of Two Calcium Uranates α‐Ca3UO6 and Ca2UO5
The structures and thermal responses of the calcium uranates α‐Ca3UO6 and Ca2UO5 were investigated using in situ synchrotron x‐ray diffraction and neutron powder diffraction. Despite the very similar chemical compositions, the structural response of the two calcium uranates is shown to be complex and varied.
Maria K. Nicholas +8 more
wiley +1 more source
X-Box Binding Protein 1 Regulates Osteogenesis of Periodontal Ligament Cells During Aging by Modulating P53 Signaling Pathway. [PDF]
Zheng Y +5 more
europepmc +1 more source
Stable Cyclic Peterson Olefination Intermediates
We present the first synthesis and characterization of several stable cyclic Peterson olefination intermediates with four carbon bonded substituents at the silicon. The cyclic 1,2‐oxasiletanide intermediates were synthesized via the reaction of an α‐silyl carbanion with various ketones.
Julia Landwehrmann +3 more
wiley +1 more source
Comparing the expression patterns and differences of LOX and LOXL1 during the development of myodural bridge and ligamentum flavum. [PDF]
Sun YT +11 more
europepmc +1 more source
[Ti(py)4I2] as an Entry Point to Titanium(II) Chemistry via Titanium Metal Oxidation
A strategically novel approach based on the oxidation of Ti metal enables access to Ti(II) chemistry. Controlled formation and complexation of Ti diiodide affords the Ti(II) complex [Ti(py)4I2], which serves as a convenient entry point to Ti(II) compounds.
Alexander Sedykh
wiley +1 more source

