Results 71 to 80 of about 128,004 (334)

Heterogeneous reactions of particulate matter-bound PAHs and NPAHs with NO3/N2O5, OH radicals, and O3 under simulated long-range atmospheric transport conditions: reactivity and mutagenicity. [PDF]

open access: yes, 2014
The heterogeneous reactions of ambient particulate matter (PM)-bound polycyclic aromatic hydrocarbons (PAHs) and nitro-PAHs (NPAHs) with NO3/N2O5, OH radicals, and O3 were studied in a laboratory photochemical chamber. Ambient PM2.5 and PM10 samples were
Arey, Janet   +8 more
core   +2 more sources

Principles for Rigorous Design and Application of Synthetic Microbial Communities

open access: yesAdvanced Science, EarlyView.
SynComs are artificially designed to enable inter‐species metabolic interactions, metabolic division of labor, and ecological interactions that can elicit phenotypes like colonization stability and environmental adaptation. This systematic review explores the processes used to construct SynComs, the assessment of the mechanisms of metabolic interaction
Yuxiao Zhang   +21 more
wiley   +1 more source

The 5.25 & 5.7 $\mu$m Astronomical Polycyclic Aromatic Hydrocarbon Emission Features

open access: yes, 2008
Astronomical mid-IR spectra show two minor PAH features at 5.25 and 5.7 $\mu$m (1905 and 1754 cm$^{\rm - 1}$) that hitherto have been little studied, but contain information about the astronomical PAH population that complements that of the major ...
A. G. G. M. Tielens   +33 more
core   +1 more source

Marine crude-oil biodegradation: a central role for interspecies interactions [PDF]

open access: yes, 2012
The marine environment is highly susceptible to pollution by petroleum, and so it is important to understand how microorganisms degrade hydrocarbons, and thereby mitigate ecosystem damage. Our understanding about the ecology, physiology, biochemistry and
Folwell, Benjamin D   +3 more
core   +1 more source

Stimuli‐Responsive Supramolecular Biomaterials for Cancer Theranostics

open access: yesAdvanced Science, EarlyView.
The ultimate goal of cancer theranostics is to get imaging agents and therapeutic cargo to tumor sites when and where they are required. “Smart” systems should be developed. This review discusses the characteristics of physiological stimuli, types and action modes of external stimuli, construction approaches and working principles, as well as ...
Wenting Hu   +4 more
wiley   +1 more source

Effects of supergene geochemical processes on desorption and bioavailability of polycyclic aromatic hydrocarbons in soil of karst area

open access: yesEnvironmental Pollutants & Bioavailability, 2021
Supergene geochemical processes (SGPs) occur ubiquitously in the Earth´s surface, but their effects on the fate and bioavailability of polycyclic aromatic hydrocarbons (PAHs) in soil remain unclear.
An Xianjin   +3 more
doaj   +1 more source

GOT1 Inhibition Induces Extracellular Matrix Remodeling in Pancreatic Cancer

open access: yesAdvanced Science, EarlyView.
Using tumor tissue engineering, we recreated pancreatic cancer and found that inhibiting glutamic‐oxaloacetic transaminase 1 (GOT1) induces extracellular matrix remodeling and secretome rewiring, as well as promotes cell death. ABSTRACT Pancreatic cancer cells rely on glutamine to sustain their survival in the stiff and poorly vascularized tumor ...
Rodrigo Curvello   +10 more
wiley   +1 more source

Dual Circularly Polarized Luminescence from Chiral Boron‐Embedded Polycyclic Aromatic Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Boron‐embedded polycyclic aromatic hydrocarbons featuring an asymmetric boron center coordinated by a proximal P═O group were synthesized. Anthracene‐fused boracyclic derivatives show dual circularly polarized luminescence (CPL) arising from excited‐state P═O⋯B dissociation, which converts point chirality into C−B axial chirality.
Tatsuya Mori   +6 more
wiley   +2 more sources

Experimental and theoretical study on the infrared spectroscopy of astrophysically relevant PAH derivatives 2- and 9-vinylanthracene

open access: yes, 2012
We propose to evaluate the contribution of polycyclic aromatic hydrocarbon molecules that carry side groups to the mid-infrared emission spectra. Within this framework, the IR absorption spectra of 2- and 9-vinylanthracene were measured in Ar matrices at
Henning, Thomas   +4 more
core   +1 more source

Metastable π‐Lithium Supermolecule Entities Govern Voltage in Electron‐Rich Electrolytes: Orbital Energetics as Predictive Voltage Descriptors

open access: yesAdvanced Science, EarlyView.
Solvated electron supermolecules (SMEs) formed by polycyclic aromatic hydrocarbon (PAH), Li⁺, and tetrahydrofuranmodulate voltage in lithium solutions. The open‐circuit‐voltage (OCV) of such solutions correlates with the lowest unoccupied molecular orbital energy of PAH, enabling high‐throughput screening for high‐voltage electrolytes.
Yiwei Feng   +3 more
wiley   +1 more source

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