PREPARATION OF PALLADIUM NANOPARTICLES ON CARBON SUBSTRATES IN AUTOCLAVE CONDITIONS
The palladium nanoparticles are obtained by the decomposition of chloride tetraammine palladium (II) at 170 C under autoclave conditions and are characterized by complex modern physico-chemical methods.
R. V. Borisov, O. V. Belousov
doaj
Ionic Precursors Transformed Into Vinyl Acetate Synthesis Catalyst via Reaction‐Driven Restructuring
This work demonstrates that a simple physical mixture of Pd and Au ionic precursors, KOAc promoter, and SiO2 support can transform into a highly active vinyl acetate synthesis catalyst through reaction‐driven restructuring. The results highlight reaction‐induced restructuring as an innovative and sustainable catalyst design strategy.
Byeong Jun Cha +11 more
wiley +1 more source
Alkyl-to-Alkyl Palladium Migration Enables Remote C-C Bond Formation. [PDF]
Kuang Y, Zhou D, Tomanik M.
europepmc +1 more source
A multifunctional structural power composite is developed by integrating high‐mass‐loading Zn‐ion hybrid supercapacitors with metal mesh current collectors and aramid nanofiber‐based composite electrolytes, enabling simultaneous load‐bearing capability and enhanced areal energy storage.
Yuseung Choi +8 more
wiley +1 more source
Dipyrromethane-diphosphines: nickel and palladium complexes as catalysts for the selective hydroboration of CO<sub>2</sub> to methoxyborane under mild conditions with mechanistic study. [PDF]
Gupta R, Kumar A, Mani G.
europepmc +1 more source
A systematic review is conducted to assess the influence of electrode architecture across micro‐ to mesoscopic length scales on electron‐transfer pathways in electrocatalysis. We discuss the structure‐activity relationships in electrocatalytic applications, including resource recovery and environmental remediation, and provide cost‐effective, efficient
Manshu Zhao +6 more
wiley +1 more source
Synthesis and sorption performance of imidazole-based hydrogels for selective palladium recovery in green hydrometallurgical processes. [PDF]
Alrashdi S +5 more
europepmc +1 more source
Two Coexisting Pathways to Volatility in Valence‐Change Memory Devices
Volatile VCM‐type memristive devices exhibit current relaxation after resistive switching, but their microscopic origin remains debated. Using pulsed measurements and a new Tunnel‐DLTS approach on Pt/SrTiO3/Nb:SrTiO3 devices, we show that post‐SET volatility is predominantly ionic, while electronic contributions—arising from quasi‐Fermi‐level ...
Johannes Hellwig +3 more
wiley +1 more source
Substituent Effects on the Stability of Pd-NHC Complexes: Switching From Molecular to "Cocktail-Type" Catalysis. [PDF]
Naumovich VO, Gordeev EG, Ananikov VP.
europepmc +1 more source
Carbon dots‐supported single‐atom catalysts provide a model platform for uncovering how coordination interactions regulate catalytic reactivity. Thiol binding at Ru‒N4 centers reshapes the reaction energy landscape of H2O2 activation, dynamically modulating ROS‐generation pathways through electronic‐structure perturbation.
Yihong Chen +11 more
wiley +1 more source

