We report a new synthesis of phenanthridines based on palladium-catalyzed picolinamide-directed sequential C–H functionalization reactions starting from readily available benzylamine and aryl iodide precursors.
Ryan Pearson +4 more
doaj +1 more source
The Pursuit of Effective Catalysis for C-C and C-N Cross-Coupling under Mild Conditions
Homogeneous transition metal-catalysis has had a great impact on the synthesis of organic molecules in recent years. The selective mono-arylation of small molecules, a class of reactions predominantly achieved via transition metal-catalyzed cross ...
MacQueen, Preston
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Preparo de Pd-NPS estabilizadas por líquidos iônicos quirais derivados de aminoácidos e aplicação em catálise de reações assimétricas de Henry [PDF]
Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2014.O presente trabalho relata a síntese e caracterização de uma série de líquidos iônicos ...
Silva, Tábata Regina
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Palladium-Catalyzed meta-C–H Functionalization of Masked Aromatic Aldehydes
Palladium-catalyzed meta-C–H functionalization enabled by transient mediators has the potential to extend the utility of directed ortho-C–H functionalization to remote positions.
Peng Wang +7 more
core +1 more source
Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen +7 more
wiley +1 more source
Cobalt particle size effects in catalysis [PDF]
Aim of the work described in this thesis was first to investigate cobalt particle size effects in heterogeneous catalysis. The main focus was to provide a deeper understanding of the origin of the cobalt particle size effects in Fischer-Tropsch (FT ...
Inorganic Chemistry and Catalysis +2 more
core +1 more source
Elucidating Mechanisms of Palladium and Iridium Catalysis using Parahydrogen [PDF]
This thesis aims to elucidate mechanisms of palladium and iridium catalysis using para-H2. In palladium catalysis, the debate on the nature of the active catalysts tends to focus on homogeneous palladium monomers or heterogeneous palladium nanoparticles;
Appleby, Kate Mary
core +3 more sources
2D Abrupt Nano‐Junctions Blending sp–sp2 Bonds on Atomically Precise Heterostructures
A lateral heterostructure between atomically precise sp–sp2$^2$ metalated graphdiyne and sp2$^2$ graphene nanoribbons is realized by on‐surface synthesis and investigated by STM and DFT. The impact of on‐surface synthesis byproducts on covalent junction formation yield is unveiled.
Alice Cartoceti +10 more
wiley +1 more source
Decoding Synergistic Pathways in Bimetallic MOFs for Advanced Oxidation Processes
This review presents a unified framework linking metal pairing and framework design with electronic structure, redox cycling, oxidant activation, reactive‐species generation, and catalytic performance across photocatalytic and oxidant‐based BMOF‐AOPs. The resulting design principles guide the development of hydrolytically stable and efficient BMOFs for
Karim El‐Naggar +2 more
wiley +1 more source
Palladium-Carbon sigma-bonded Complexes
This chapter provides a comprehensive review of the literature (1982-1994) for organopalladium chemistry covering those compounds containing palladium to carbon sigma bonds.
Canty, AJ (15913241)
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