Results 211 to 220 of about 10,174 (239)

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Size Matters: Barrier Heights and Widths in the Kinetics Of Tautomerisation and Rotamerisation of Thiotropolone and Its Five‐ and Three‐Membered Cyclic Analogues

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Recent experiments by Nunes et al. have demonstrated that unprecedented control of chemical reactions is possible by narrowband infrared vibrational photo‐excitation at low temperatures in inert matrices. The generated higher energy level conformers may then undergo rotamerisation and tautomerisation reactions which provide extremely useful ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

Dynamic coronal plane knee alignment: Femoral anatomy determines kinematic curve morphology, tibial anatomy determines curve position

open access: yesKnee Surgery, Sports Traumatology, Arthroscopy, EarlyView.
Abstract Purpose A single hip–knee–ankle angle (HKA) angle does not reflect the biomechanics of native, arthritic or prosthetic knees. Since HKA varies throughout flexion, dynamic coronal alignment is best represented by a kinematic curve plotting HKA against the range of motion.
Petros Ismailidis   +3 more
wiley   +1 more source

Microbiological Mechanisms of Sand‐Mixed Soil Improvement in Continuously Cropped Soil

open access: yesLand Degradation &Development, EarlyView.
ABSTRACT Sand‐mix soil is a widely adopted method for soil improvement in agricultural production. However, beyond the evident enhancement of physical structure, the mechanisms by which sand‐mix soil promotes crop root growth by influencing soil physicochemical properties and microbial communities remain insufficiently understood.
Yue Huang   +11 more
wiley   +1 more source

Optimal pace timing for left bundle branch area pacing with or without an additional LV lead: results from the CSPOT study. [PDF]

open access: yesEuropace
Schaller RD   +16 more
europepmc   +1 more source

Broadband Mode Converter With Customizable Modal Ratio Leveraging Subwavelength Engineering for Advanced Multimode Silicon Photonics

open access: yesLaser &Photonics Reviews, EarlyView.
This work introduces a customizable mode converter for multimode silicon photonics, enabling precise control over the conversion ratio between optical modes. The device operates across a broad wavelength range (1350–1700 nm) with 15 distinct conversion levels.
Raquel Fernández de Cabo   +7 more
wiley   +1 more source

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