Results 121 to 130 of about 16,953 (302)

Impurity Tolerance in LiFePO4 Cathodes: Contrasting Structural, Electronic, and Electrochemical Roles of Residual Ni and Cr

open access: yesAdvanced Science, EarlyView.
Impurity tolerance in LiFePO4 cathodes varies strongly with impurity type and content. Low Ni levels are accommodated within the lattice with minimal structural disruption, whereas higher Ni contents introduce antisite disorder. In contrast, Cr impurities segregate from the LiFePO4 framework, blocking lithium‐ion pathways and leading to inferior ...
Minjin Kim   +3 more
wiley   +1 more source

A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones

open access: yesAdvanced Science, EarlyView.
Low‐substitution‐order silylium ions (R2HSi+) exhibit exceptional Lewis acidic activity. We report diethylsilylium‐catalyzed reductive sulfonamidation of functionalized ketones to access β‐amino esters. The in situ generated ion pair shows enhanced reactivity, with diethylsilane serving as both reductant and precatalyst. The developed protocol proceeds
Woo Hee Kim   +5 more
wiley   +1 more source

O ORÇAMENTO PARTICIPATIVO E O PAPEL DO ESTADO – THE PARTICIPATORY BUDGET AND THE ROLE OF THE STATE

open access: yesRevista da Seção Judiciária do Rio de Janeiro, 2010
O retorno da democracia direta é objeto do debate político mundial. A repulsa da população pela política e pelas atuais formas de democracia representativa traz a reflexão sobre novas formas de participaç ...
Gabriela Soares Balestero
doaj  

Sub‐Terahertz Memristor Switches Using MoS2 by Liquid–Liquid Interface Assembly

open access: yesAdvanced Science, EarlyView.
This work introduces application‐ready sub‐terahertz memristor switches fabricated from electrochemically exfoliated MoS2 nanosheets assembled at a liquid–liquid interface. The devices exhibit robust unipolar resistive switching, low insertion loss, and high isolation across 10–110 GHz.
Tomás Mingates   +15 more
wiley   +1 more source

Democracy and education

open access: yes, 2022
This chapter considers the important relationship between education and democracy in contemporary democratic societies. Although lauded as an inclusive and participatory system of social and political governance, democracy remains a contested concept ...
Riddle, Stewart
core  

Os sentidos e desafios da participação

open access: yesCiências Sociais Unisinos, 2006
This article analyzes some challenges and difficulties of the participatory experiences in Brazil – particularly of the Managing Councils and the Participatory Budgeting – in constituting themselves as experiences of deliberative democracy.
Lígia Helena Hahn Lüchmann
doaj  

In Situ Confinement of 0D Halometallates Within Deep Eutectic Solvents: From Systematic Screening to Metal‐Tunable Luminescence for Anti‐Counterfeiting Eutectogels

open access: yesAdvanced Science, EarlyView.
We report photostable, photoluminescent deep eutectic solvents (DESs) powered by in situ‐formed zero‐dimensional (0D) halometallates. Stabilized by microenvironment‐controlling hydrogen bond acceptor (HBA) and donor (HBD) networks, these DESs exhibit vibrant, metal ion‐tunable emission (PLQY = 60.2%).
Jeesu Moon   +4 more
wiley   +1 more source

'This is what democracy looks like' : New Labour's blind spot and peripheral vision

open access: yes, 2006
New Labour in government since 1997 has been roundly criticized for not possessing a clear, coherent and consistent democratic vision. The absence of such a grand vision has resulted, from this critical perspective, in an absence of 'joined-up' thinking ...
Judge, David, David Judge
core   +1 more source

Circulating Amino Acid Network Remodeling Reveals Systemic Metabolic Reprogramming Predictive of Colorectal Cancer Recurrence and Metastasis

open access: yesAdvanced Science, EarlyView.
Blood‐based amino acid patterns measured by 19F NMR reveal hidden metabolic changes in colorectal cancer. By analyzing how these amino acids interact as a network, machine learning models identify patients at higher risk of recurrence and metastasis.
Ji‐Yeon Lee   +9 more
wiley   +1 more source

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