Advanced Functional Materials, EarlyView.A strategic spin‐polarization suppression in Fe single‐atom catalysts is proposed to enhance electrocatalytic reduction of NO to NH3. Employing a top‐down electrospinning strategy, self‐supported FeSAC with Fe‐N3S1 coordination structure and spin‐state transition is engineered from high‐spin to low‐spin.
Jialing Song +13 more
wiley +1 more source
Statistical Mechanics of Linear <i>k</i>-mer Lattice Gases: From Theory to Applications. [PDF]
Entropy (Basel)Riccardo JJ +3 more
europepmc +1 more source
Lithium Intercalation in the Anisotropic Van Der Waals Semiconductor CrSBr
Advanced Functional Materials, EarlyView.We report the lithium intercalation in the layered van der Waals crystal CrSBr, revealing strongly anisotropic ion‐migration dynamics. Optical and electrical characterization of exfoliated CrSBr shows lithium diffusion coefficients that differ by more than an order of magnitude along a‐ and b‐directions, consistent with molecular dynamics simulations ...
Kseniia Mosina +13 more
wiley +1 more source
Observation of anomalous decay of a polarized three-component Fermi gas. [PDF]
Nat CommunSchumacher GL +7 more
europepmc +1 more source
Artificial Amorphous Interface Matters for Boosting High‐Voltage Stable LiCoO2 Cathode
Advanced Functional Materials, EarlyView.The amorphization of phosphate‐based surface layer with favorable Li‐ion conducting kinetics is realized by precisely tailored atomic‐level fabrication. This amorphous coating enables the lithium cobalt oxide (LCO) cathode superior high‐voltage rate capability and cycling performance, owing to the fast interfacial ionic transport and maintained ...
Jinjin Ma +10 more
wiley +1 more source
Multiscale reaction model coupling dual-site microkinetics with bulk diffusion and CFD-DEM for a perovskite oxygen carrier. [PDF]
Front ChemWang R, Li Z, Liu L.
europepmc +1 more source
Charge Transport in Ternary Charge‐Transfer Solid Solution Single Crystals
Advanced Functional Materials, EarlyView.This study deconvolutes the roles of indirect (superexchange) and direct electronic coupling on charge transport in single crystals of an organic charge‐transfer molecular semiconductor (OSC). This model system elegantly demonstrates that structural defects introduced by chemical dopants play a significant role in the electronic performance ...
Jonathan C. Novak +7 more
wiley +1 more source
Characterization and Preparation of Nanostructured Al<sub>2</sub>Fe<sub>3</sub>Si<sub>3</sub> Thermoelectric Materials. [PDF]
Materials (Basel)Zhao Z, Ikeda T.
europepmc +1 more source
Chiral SURMOFs for Vibrational Circular Dichroism: Multiscale Modeling and Experimental Insights
Advanced Functional Materials, EarlyView.The use of solid‐state vibrational circular dichroism (VCD) for MOFs is still somewhat unexplored, and in this work, it is shown that chiral surface‐anchored MOFs (SURMOFs) grown on CaF2 provide an excellent platform for VCD. Experimental results are validated through multiscale modeling, showing strong agreement across multiple spectroscopic ...
Ana C. Fingolo +9 more
wiley +1 more source
Dynamic behavior of molecular Pd-acetate trimers and dimers in heterogeneous vinyl acetate synthesis. [PDF]
Nat CommunJacobs HP +14 more
europepmc +1 more source