Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez +3 more
wiley +1 more source
Semi-Physiological Population Pharmacokinetic Modeling of Oral and Intravenous Paracetamol to Quantify Presystemic Metabolism and Enterohepatic Recirculation. [PDF]
Lau C +10 more
europepmc +1 more source
Porphyrin‐Geländer–Helical Conjugated Banister Type Porphyrin Dyads
Porphyrin arrays go chiral–A porphyrin Geländer macrocycle represents the intriguing prototype architecture of helically chiral butadiyne‐linked porphyrin arrays. This study combines synthetic, spectroscopic, and computational methods to shed light on its structure, chiroptical properties, and tunability, highlighting its promise for advancing ...
Joël F. Keller +2 more
wiley +1 more source
Protective effects of <i>Lagerstroemia speciosa</i> against paracetamol-induced renal and testicular toxicity in rats via antioxidant, anti-inflammatory, and anti-apoptotic mechanisms. [PDF]
Elsheshtawy NE +9 more
europepmc +1 more source
A phosphinine–borane Lewis pair shows a dynamic mode of water addition, revealing reversible and regioselective transformations that expand the reactivity of aromatic phosphorus heterocycles and open pathways to stimuli‐responsive systems for catalysis, small‐molecule activation, and functional materials.
Samantha Frank +7 more
wiley +1 more source
The clinical efficacy of pocket creation method ESD and conventional ESD in the treatment of early colorectal neoplasms: a meta-analysis. [PDF]
Jiekang K, Zhang L, Chen G.
europepmc +1 more source
A strategy for the Pt/TiO2‐photocatalyzed β‐scission of nonactivated 3° alcohols in the absence of external oxidants and additives was developed. A wide variety of C‐centered radicals were generated and subsequently engaged in C─C bond‐forming reactions.
Shu Sakurai +3 more
wiley +1 more source
Effect of fins in enhancing phase change material fusion in a spherical thermal energy storage container. [PDF]
Swami Punniakodi BM +7 more
europepmc +1 more source
The energetics of the addition reaction of P‐centered radicals onto alkenes are primarily ruled by the stability of the attacking radical, as outlined by the computational screening of a wide range of reactions. In addition, donor‐acceptor substituents at the olefin have an important tuning role.
Meng Yang +2 more
wiley +1 more source
On-Going into Green Buildings: Hybridized Bimetallic Iron Ferrite Scheme for Superior Performance in a Pilot-Scale Solar Energy Storage System. [PDF]
Nour MM, Tony MA, Nabwey HA.
europepmc +1 more source

