Results 141 to 150 of about 81,707 (278)

Synthesis of Carbon Nanotubes From CO2 Enabled by Fe–Mo Bimetallic Catalysts via Effective CO2 Scavenging

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The tandem process involves CO2 methanation and CH4 pyrolysis for CNT synthesis. Unreacted CO2 and H2 from methanation oxidize Fe, suppressing CNT growth on Fe‐only catalysts. Incorporation of Mo into Fe/MgO forms Mo2C, which prevents Fe oxidation under CO2/H2 conditions and thereby enables CNT formation.
Eunchae Oh   +5 more
wiley   +1 more source

Synthesis, Crystal Structure, and Optoelectronic Properties of [(n‐/tert‐C4H9)S(CH3)2]PbI3

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Reaction of two isomers of butyldimethylsulfonium cation with PbI2 using solid‐state and solution methods yielded the corresponding organic/inorganic hybrid compounds with high humidity tolerance and 1D crystal structures of [n‐C4H9S(CH3)2]PbI3 and [tert‐C4H9S(CH3)2]PbI3.
Ioannis Koutsoumpogeras   +4 more
wiley   +1 more source

Design, Synthesis, and Photophysical Studies of Functionalized Polyaromatic Isonitriles as Visible Light Photoredox Catalysts

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini   +9 more
wiley   +1 more source

Non‐Uniform Programmable Photonic Waveguide Meshes

open access: yesLaser &Photonics Reviews, EarlyView.
Integrating defect cells into uniform hexagonal waveguide meshes overcomes the fundamental spectral and temporal limitations of programmable photonics. By leveraging the Vernier effect through non‐uniform coupled cavities, this architecture achieves a tenfold increase in free spectral range and ultra‐fast sampling times, paving the way for next ...
Cristina Catalá‐Lahoz, José Capmany
wiley   +1 more source

Reactive Preservation of Carbonate in Earth's Mantle Transition Zone

open access: yesGeophysical Monograph Series, Page 167-177., 2020

This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.

Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions

Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Jie Li   +3 more
wiley  

+1 more source

Chain‐End Grafting of RAFT Polyelectrolyte Macroligands to Stabilize Near‐Infrared‐Emitting Gold Nanoclusters

open access: yesMacromolecular Rapid Communications, EarlyView.
Surface‐functionalized gold nanoclusters (AuNCs) are synthesized in situ by chain‐end grafting of RAFT polyelectrolytes at room temperature directly in water. It leads to highly stable polymer‐AuNCs nanohybrids emitting near‐infrared photoluminescence with µs lifetimes. ABSTRACT With their photoluminescence properties, gold nanoclusters (AuNCs, d<2 nm)
Bárbara Casteleiro   +7 more
wiley   +1 more source

First 20 Years of Orbitrap Mass Spectrometry as the Mainstream Analytical Technique

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT This review traces the first 20 years of Orbitrap mass spectrometry as a mainstream high‑resolution and accurate‑mass (HR/AM) technology. It outlines the historical development of the Orbitrap analyzer, the evolution of major instrument families, and the key technological innovations that enabled its widespread adoption. Particular emphasis is
Alexander Makarov
wiley   +1 more source

Compatibilization and Reinforcement of PHB/PBAT Blends via Sequential Blending of Surface‐Modified Cellulose

open access: yesPolymer Engineering &Science, EarlyView.
Sequential blending improved the mechancial properties of PHB/PBAT/cellulose composites as compared to the one‐step batch mixing method. ABSTRACT Polyhydroxybutyrate (PHB) is a natural and biodegradable polymer generated by bacteria. While its applications to potentially replace petroleum‐based plastics are severely limited due to its brittleness and ...
Wai Hin Lee   +3 more
wiley   +1 more source

The Mycobacterium tuberculosis Rv0132c Gene Product Mtb‐FGD2 Can Act as an F420‐Dependent Glucose Dehydrogenase

open access: yesProteins: Structure, Function, and Bioinformatics, EarlyView.
ABSTRACT The role of the cell envelope‐associated Rv0132c/FGD2 from Mycobacterium tuberculosis has long been a subject of debate. Importantly, FGD2 is found only in pathogenic mycobacteria, making it a potential drug target. While some suggest it functions as a glucose‐6‐phosphate dehydrogenase, others propose it acts instead as an F420‐dependent ...
Adewale V. Aderemi   +12 more
wiley   +1 more source

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