A General Approach for Strained Ring Functionalization via Nucleophilic Catalysis. [PDF]
Wang P +7 more
europepmc +1 more source
Light‐Induced Reactions of Small‐Membered Cyclic Carbonyl Compounds
This review highlights recent advances in the synthesis and photochemical reactivity of cyclopropenone and cyclobutenedione. These compounds undergo photolysis upon direct excitation, and in some cases, through indirect excitation by photocatalysts. The resulting photogenerated species exhibit unique reactivity profiles that are strongly influenced by ...
Kenji Mishiro
wiley +1 more source
Synthesis of Fused-Housane Derivatives via Intramolecular [2 + 2] Photocycloaddition. [PDF]
Suárez-García D +3 more
europepmc +1 more source
Three-dimensional saturated C(sp3)-rich bioisosteres for benzene. [PDF]
Tsien J, Hu C, Merchant RR, Qin T.
europepmc +1 more source
Light-enabled scalable synthesis of bicyclo[1.1.1]pentane halides and their functionalizations. [PDF]
Ripenko V +16 more
europepmc +1 more source
Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides. [PDF]
Howlett WP +5 more
europepmc +1 more source
Redox-active inverse crowns for small molecule activation. [PDF]
Maurer J +7 more
europepmc +1 more source
A method for synthesizing sulfur‐substituted cyclohexenes is reportedthat leverages the η2‐coordination of a phenyl sulfone to [WTp(NO)(PMe3)] (Tp = trispyrazolylborate). Three sequential protonation and nucleophilic additions to the bound arene, followed by oxidative decomplexation, affords functionalized cyclohexenes bearing sp3‐ and sulfur‐enriched ...
Daniel J. Siela +3 more
wiley +1 more source
A General Metallaphotoredox Platform for <i>N</i>-Alkylated Sulfoximines as Bioisosteric Building Blocks. [PDF]
Großkopf JJ +3 more
europepmc +1 more source

