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Formation of a solid solution in the MgSiO3–MnSiO3 perovskite system
Physics and Chemistry of Minerals, 2013Experiments using laser-heated diamond anvil cells combined with synchrotron X-ray diffraction and SEM–EDS chemical analyses have confirmed the existence of a complete solid solution in the MgSiO3–MnSiO3 perovskite system at high pressure and high temperature.
Lin Li +5 more
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J. Chem. Soc., Dalton Trans., 1983
A detailed study has been made of supertransferred hyperfine field (s.t.h.f.) effects at 119Sn doped into various perovskites with the formula (A0.95Ca0.05)(Fe0.85M0.10Sn0.05)O3 with A = La, Eu, or Lu and M = Al, Ga, Sc, Cr, Mn, Co, or Ni. The observed s.t.h.f.
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A detailed study has been made of supertransferred hyperfine field (s.t.h.f.) effects at 119Sn doped into various perovskites with the formula (A0.95Ca0.05)(Fe0.85M0.10Sn0.05)O3 with A = La, Eu, or Lu and M = Al, Ga, Sc, Cr, Mn, Co, or Ni. The observed s.t.h.f.
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Planar Defects and Incommensurate Phases in Highly Ordered Perovskite Solid Solutions
Physical Review Letters, 2002A first-principles-derived approach is used to study the effects of planar defects on structural properties of a rocksalt-ordered Pb(Sc0.5Nb0.5)O3 alloy. These defects lead to unusual features, including a less symmetrical ground state with respect to the perfectly ordered material.
Igor A, Kornev, L, Bellaiche
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Oxyhydrides of (Ca,Sr,Ba)TiO3 Perovskite Solid Solutions
Inorganic Chemistry, 2012The oxyhydride solid solutions (Ca,Sr)TiO(3-x)H(x) and (Sr,Ba)TiO(3-x)H(x) have been prepared by reducing the corresponding ATiO(3) oxides with calcium hydride. Under the reaction conditions examined, a hydride content of x = 0.1-0.3 was obtained for all compositions. Compared to our previous result with BaTiO(3-x)H(x), the larger particle size in this
Tatsunori Sakaguchi +16 more
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Electrophysical properties of perovskite solid solutions in the system CaTiO3−La2O3
Refractories and Industrial Ceramics, 1998The electrophysical properties of perovskite solid solutions in the system CaTiO3−La2O3 were investigated in the La2O3 concentration range of 0–40%. The composition dependences of permittivity, loss tangent, volume resistivity, and temperature coefficient of capacitance were plotted.
V. I. Strakhov +4 more
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Microheterogeneous Solid Solutions in Perovskites: Formation, Microstructure, and Catalytic Activity
ChemInform, 2004AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
L. A. Isupova +5 more
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Phase Transitions in Perovskite Solid Solutions with Incipient Ferroelectrics
Ferroelectrics, 2004The impurity-induced ferroelectric phase transitions in incipient perovskite ferroelectrics are discussed along with improper ferroelastic phase transitions. It is shown that the critical concentration of impurities is proportional to 1/ϵ3/2 and that the ferroelectric phase transitions probably suppress ferroelastic transitions.
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Mössbauer Studies of BiFeO3-PbTiO3 Perovskite-Type Solid Solutions
Journal of Applied Physics, 1971The Mössbauer spectra of the ferroelectric solid solutions (BiFeO3)x(PbTiO3)1−x have been studied as a function of temperature, mainly between room temperature and 600°C, using 57Fe in the solutions as an absorber. The quadrupole splitting increased and the isomer shift decreased between x=0.05 and x=0.70, a range in which the solutions are tetragonal ...
C. M. Yagnik, R. Gerson, W. J. James
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Solid solution range of boron and properties of the perovskite-type NdRh3B
Journal of Alloys and Compounds, 2002Abstract Polycrystalline samples of NdRh 3 B x have been synthesized by arc melting technique. The crystal structure of NdRh 3 B x is the perovskite-type cubic system (space group Pm 3 m ) for nominal boron concentration in the range of 0.706≤ x ≤1.000 (15–20 mol.% B). The lattice parameter a varies linearly from 0.41749(7) nm ( x =0.706)
Toetsu Shishido +12 more
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Investigations on magnetically diluted KNixMg1–xF3 perovskite solid solution
Physica Status Solidi (a), 1988The magnetic properties and EPR spectra of magnetically diluted KNixMg1−xF3 perovskite solid solutions are examined. The susceptibility measurements show that these compounds are isotropic antiferromagnetic materials at high nickel concentrations. A critical concentration is found to be x = 0.4.
D. Skrzypek +2 more
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