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Peroxymonosulfate Activation by BaTiO3 Piezocatalyst

open access: yesCatalysts, 2022
Peroxymonosulfate (PMS) plays an important role in the advanced oxidation process for environmental remediation. In this study, barium titanate (BTO) piezocatalyst was selected for the activation of PMS driven by ultrasonic power. The degradation of Rhodamine B (RhB) by BTO single component, PMS single component, and BTO/PMS double components were ...
Jinlong Wang, Tian Hou
exaly   +4 more sources
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Activation of Peroxymonosulfate by Subsurface Minerals

Journal of Contaminant Hydrology, 2016
In situ chemical oxidation (ISCO) has become a widely used technology for the remediation of soil and groundwater. Although peroxymonosulfate is not a common oxidant source for ISCO, its chemical structure is similar to the ISCO reagents hydrogen peroxide and persulfate, suggesting that peroxymonosulfate may have the beneficial properties of each of ...
Amy Teel
exaly   +3 more sources

Improvement of peroxymonosulfate utilization efficiency for sulfamethazine degradation by photo-electron activating peroxymonosulfate: Performance and mechanism

Journal of Colloid and Interface Science, 2023
Enhancing the utilization efficiency of oxidant is of great importance for advanced oxidation processes (AOPs). Herein, nitrogen-doped titania dioxide/carbon (NTC7) catalyst was fabricated via pyrolyzing NH2-MIL-125 under nitrogen atmosphere at 700 °C.
Lanyue, Qi   +8 more
openaire   +2 more sources

Evolution of Singlet Oxygen by Activating Peroxydisulfate and Peroxymonosulfate: A Review [PDF]

open access: yesInternational Journal of Environmental Research and Public Health, 2021
Advanced oxidation processes (AOPs) based on peroxydisulfate (PDS) or peroxymonosulfate (PMS) activation have attracted much research attention in the last decade for the degradation of recalcitrant organic contaminants. Sulfate (SO4•−) and hydroxyl (•OH) radicals are most frequently generated from catalytic PDS/PMS decomposition by thermal, base ...
Jianguo Bao, Jiangkun Du
exaly   +3 more sources

Activation of peroxymonosulfate by bicarbonate and acceleration of the reaction by freezing

Science of The Total Environment, 2021
This study demonstrates the positive effects of dissolved bicarbonate and carbonate anions on peroxymonosulfate (PMS) induced oxidation and the remarkable acceleration of the reaction by freezing. More than 90% of the initial 4-chlorophenol (4-CP) decomposed in the frozen case, whereas only less than 20% of the 4-CP was removed in the aqueous case in ...
Yong-Yoon, Ahn, Jungwon, Kim, Kitae, Kim
openaire   +2 more sources

Molecular vibrational spectra of potassium peroxymonosulfate, KHSO5 and KHSO5 · H2O, and of the aqueous peroxymonosulfate ion

Spectrochimica Acta Part A: Molecular Spectroscopy, 1985
Both i.r. and Raman spectra of solid anhydrous KHSO5 and KHSO5 · H2O were measured, along with the Raman spectrum of the peroxymonosulfate ion, HSO−5, in aqueous solution. A normal coordinate analysis of the ion was carried out, and the fundamental frequencies and force constants are compared with those of the isoelectronic fluoroxysulfate ion, SO4F−.
Evan H Appelman   +3 more
openaire   +1 more source

Chloride promoted oxidation of tritosulfuron by peroxymonosulfate

open access: yesChemical Engineering Journal, 2018
MINECO of Spain (CTQ2015/64944-R)
Rafael Rodríguez Solis, Javier Rivas
exaly   +3 more sources

The standard enthalpy of formation of peroxymonosulfate (HSO5−) and the standard electrode potential of the peroxymonosulfate-bisulfate couple

The Journal of Chemical Thermodynamics, 1982
Abstract The standard enthalpy of formation at 298.15 K of the aqueous peroxymonosulfate ion, HSO5−, has been determined by reduction of the ion in aqueous HI. The value obtained is ΔHfo(HSO5−, aq) = −(798.4 ± 2.5) kJ·mol−1. This enthalpy was combined with an estimated entropy for the aqueous ion to yield a standard electrode potential of (1.82 ± 0 ...
William V. Steele, Evan H. Appelman
openaire   +1 more source

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