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Aggregation Processes of Perylene Bisimide Diimidazolium Salts

Chemistry – A European Journal, 2015
AbstractThe supramolecular aggregation of three diimidazolium‐functionalized perylene bisimides, differing in the alkyl chain length was investigated. These salts form aggregates in solvents like chloroform, dichloromethane, and glycerol. Solvent‐, concentration‐, and temperature‐dependent spectroscopic studies were carried out, evidencing the ...
Francesca, D'Anna   +4 more
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Iridium-Catalyzed Direct Tetraborylation of Perylene Bisimides

Organic Letters, 2011
Treatment of perylene bisimides (PBIs) with bis(pinacolato)diboron in the presence of an iridium catalyst provides tetraborylated PBIs at 2,5,8,11-positions in good yields with perfect regioselectivity. The planar structure of the perylene core has been confirmed by X-ray diffraction analysis.
Takuro, Teraoka   +2 more
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Silanediol-Bay-Bridge Rigidified Axially Chiral Perylene Bisimide.

Journal of Organic Chemistry
Chiral organic molecules with a complementing π-structure are highly desired to obtain materials with good semiconducting properties and pronounced chirality effects in the visible region.
Oliver Nagler, R. K. Dubey, F. Würthner
semanticscholar   +1 more source

Perylene Bisimide-Based Luminescent Liquid Crystals with Tunable Solid-State Light Emission.

ACS Applied Materials and Interfaces, 2021
Perylene bisimides are among the most studied building blocks for supramolecular assemblies in the fabrication of optoelectronic devices for their exceptional optical and electronic properties; however, developing perylene bisimide-based luminescent ...
Bin Mu   +4 more
semanticscholar   +1 more source

Anthraceno-Perylene Bisimides: The Precursor of a New Acene

Organic Letters, 2011
A controlled synthesis strategy for a anthracene-fused perylene bisimide was developed from the cyclization of an anthracene unit pendant to a perylene diimide scaffold. The direct cyclization led to a zigzag molecule, while a Diels-Alder strategy influenced the regiochemistry of cyclization to afford the linear precursor of a new acene.
Yongjun, Li   +6 more
openaire   +2 more sources

Twisted, Z-Shaped Perylene Bisimide

Journal of the American Chemical Society, 2005
The first derivative of a new class of perylene bisimide chromophores, N,N'-bis(octyl)-3,9-bis(phenyl)perylene-1,2,7,8-tetracarboxyl bisimide, 1, has been synthesized and its fundamental photophysical and electrochemical properties assessed. The extended, Z-shaped structure was achieved by use of the classic photoenolization of an o-methylbenzophenone ...
Faysal, Ilhan   +4 more
openaire   +2 more sources

Resonance-Enhanced Two-Photon Absorption and Optical Power Limiting Properties of Three-Dimensional Perylene Bisimide Derivatives.

Journal of Physical Chemistry B, 2021
Push-pull organic structures characterized by an intramolecular charge transfer (ICT) process and π-electron delocalization are potentially interesting luminescent materials.
Wan Feng   +7 more
semanticscholar   +1 more source

Impact of Packing Geometry on Excimer Characteristics and Mobility in Perylene Bisimide Polycrystalline Films.

ACS Applied Materials and Interfaces
Efficient exciton transport is essential for high-performance optoelectronics. Considerable efforts have been focused on improving the exciton mobility in organic materials.
Seongsoo Kang   +5 more
semanticscholar   +1 more source

Efficient Multiexciton State Generation in Charge-Transfer Coupled Perylene Bisimide Dimers via Structural Control.

Journal of the American Chemical Society, 2020
The singlet fission (SF) process is generally defined as the conversion of one singlet exciton (S1) into two triplet excitons (2·T1), which has the potential to overcome thermalization losses in the field of photovoltaic devices. Given the limitations of
Yongseok Hong   +6 more
semanticscholar   +1 more source

Luminescent one-dimensional nanostructures of perylene bisimides

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2013
Perylene bisimides form a unique class of organic semiconductors, in this investigation two symmetrical perylene bisimides caped with 1-butyl (B-PTCDI) and 4,4-diethoxybutyl (DB-PTCDI) have been synthesized and characterized. The compounds self-assembled as a network of nanobelts and nanorods in the solution based self-assembly process. Morphologies of
G, Boobalan, P K M, Imran, S, Nagarajan
openaire   +2 more sources

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