Color–Tunable Triple–State “Smart” Window
Materials that rapidly change their optical properties in response to external stimuli are crucial for displays and “smart” window applications. Herein, a fluorescent red dye modified with liquid crystal (LC) side chains is described to be interactive ...
Gilles H. Timmermans +4 more
doaj +1 more source
Time-Dependent Density Matrix Renormalization Group Algorithms for Nearly Exact Absorption and Fluorescence Spectra of Molecular Aggregates at Both Zero and Finite Temperature [PDF]
We implement and apply time-dependent density matrix renormalization group (TD-DMRG) algorithms at zero and finite temperature to compute the linear absorption and fluorescence spectra of molecular aggregates.
Chan, Garnet Kin-Lic +2 more
core +3 more sources
Observation of Two-Exciton States in Perylene Bisimide Aggregates
The behavior of excitons on perylene bisimide aggregates is investigated at high excitation densities by femtosecond absorption spectroscopy. Indications for a significant population in the two-exciton manifold are found.
Lochbrunner S. +3 more
doaj +1 more source
Yellow Light-Emitting Highly Soluble Perylene Bisimide Dyes by Acetalization of Bay-Hydroxy Groups.
A new class of perylene bisimide (PBI) derivatives is introduced by bridging 1,12- and 1,6,7,12-hydroxy functionalized bay positions with oxygen-carbon-oxygen linker(s).
Oliver Nagler +7 more
semanticscholar +1 more source
Perylene Bisimide Cyclophanes: Structure–Property Relationships upon Variation of the Cavity Size
Five cyclophanes composed of two perylene bisimide (PBI) dyes and various CH2–arylene–CH2 linker units were synthesized. PM6-D3H4 geometry-optimized structures and a single crystal for one of these cyclophanes reveal well-defined distances between the ...
Jessica Rühe +4 more
doaj +1 more source
Reversible Photoreduction as a Trigger for Photoresponsive Gels [PDF]
We present here a new type of photoresponsive, reversible low molecular weight gel. All previous examples rely on a photoisomerisation, ring-closing or dimerization. We show that photoreduction of a perylene bisimide gelator results in the formation of a
Dave J. Adams +7 more
core +4 more sources
Controlled aggregation of peptide-substituted perylene-bisimides [PDF]
Controlled aggregation of perylene bisimides in multiple modes has been achieved via symmetric substitution with peptides. Using optical probes of aggregation, the balance of hydrophobic and electrostatic forces are found to play a key role in directing self assembly and are exploited via solvent, pH, and specific extrinsic ion effects.
Joseph K, Gallaher +3 more
openaire +2 more sources
Iridium-Catalyzed Direct Tetraborylation of Perylene Bisimides [PDF]
Treatment of perylene bisimides (PBIs) with bis(pinacolato)diboron in the presence of an iridium catalyst provides tetraborylated PBIs at 2,5,8,11-positions in good yields with perfect regioselectivity. The planar structure of the perylene core has been confirmed by X-ray diffraction analysis.
Takuro, Teraoka +2 more
openaire +3 more sources
The molecular orientations of conjugated materials on the substrate mainly include edge‐on, face‐on, and end‐on. Edge‐on and face‐on orientations have been widely observed, while end‐on orientation has been rarely reported.
Dongdong Xia +8 more
doaj +1 more source
Molecular Devices. Chiral, Bichromophoric Silicones [PDF]
The interaction of chromophores is proposed as a basis for the construction of devices with high complexity.
Ganachaud, Francois, Langhals, Heinz
core +1 more source

