Results 201 to 210 of about 5,505,025 (397)

Dual Photoredox/Cu‐Catalysis Enables Diastereoselective Synthesis of 3‐β‐Ethynyltropanes via Decarboxylative Alkynylation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A copper‐catalyzed decarboxylative alkynylation of tropanes is developed. This approach works under mild conditions and selectively produces a range of 3‐β‐alkynylated tropanes. Moreover, it provides a versatile and convergent platform for further functionalization of the triple bond.
Mayssa Zayene   +6 more
wiley   +1 more source

Synthesis of Polysubstituted Naphthalenes via Metal‐Free Borylative Cyclization of o‐Alkynylstyrenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A selective, metal‐free method for the synthesis of boron‐functionalized polysubstituted naphthalenes via BCl3‐mediated cyclization of α‐substituted o‐alkynylstyrenes is described. The reaction exhibits broad substrate scope, tolerating various groups such as ethers, sulfides and halogens, and delivers high yields under mild conditions, even ...
Marcos Humanes   +2 more
wiley   +1 more source

Development of Photo‐Biocatalytic Redox System for Asymmetric Synthesis of Optically Active Amines Using Blue Light and Transaminases. A Case Study Toward Mavacamten

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract α‐Chiral amines are versatile building blocks for the asymmetric synthesis of optically pure high‐added‐value chemicals, including pharmaceuticals, agrochemicals, and natural products. Herein, we report a one‐pot, two‐step sequential deracemization of racemic sec‐alcohols to optically enriched primary amines throught a photo‐biocatalytic ...
Natalia Antos   +5 more
wiley   +1 more source

Integration of Coke and CNMs with Bitumen: Synthesis, Methods, and Characterization. [PDF]

open access: yesNanomaterials (Basel)
Hashami M   +6 more
europepmc   +1 more source

Development of Hydrofluoroolefin (HFO)‐Based Direct O‐Fluoroalkenylation of Phenols Targeting Tyrosine Conjugation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Methodology for direct fluoroalkenylation of phenolic OH function was developed using a fluorinated electrophilic reagent derived from HFO1234ze gas. Besides various functionalized phenols, tyrosine and tyrosine‐based peptides were successfully conjugated under the optimized reaction conditions.
Rihárd Sisa   +2 more
wiley   +1 more source

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