Results 201 to 210 of about 397,176 (340)

Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
In the presence of a Pd0 catalyst, large π‐extended arynes trimerize in an unusual manner to forge extremely compact and strained chiral benzenoids. This new trimerization reaction involves a 1,7‐Pd isomerization, a rare and poorly understood process that is elucidated.
Albert Artigas   +6 more
wiley   +1 more source

Rhodium‐Catalyzed Oxidative CH o‐Arylation of s‐Aryltetrazines with Aryl Boronic Acids: One‐Step Selective Access to T‐Shaped and Z‐Shaped Polyaromatics

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A one‐step regioselective access to T‐Shaped and Z‐Shaped polyaromatics s‐tetrazines by a rhodium‐catalyzed oxidative CH o‐functionalization is reported. Electron‐rich aryl coupling partners display a higher reactivity than electron‐poor aryl, and allow the formation of poly(hetero)aromatic derivatives while avoiding 1,4‐azaphilic addition of the ...
Oumaima Abidi   +6 more
wiley   +1 more source

5,7‐Membered Cyclometallated Gold(III) Complexes with Pyridine‐Phenyl‐Oxazoline N^C^N Ligands as Catalysts for Organic Transformation Reactions Under Silver‐Free Conditions

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A series of 5,7‐membered cyclometallated gold(III) complexes with N^C^N tridentate ligands are prepared via transmetalation of pyridine‐phenyl‐oxazoline ligand‐containing organomercury compounds with potassium gold(III) chloride (KAuCl4) for catalysis.
Yosephine Tania Limanto   +4 more
wiley   +1 more source

Bifunctional Organocatalysts and Brønsted Bases in Cooperative Catalysis for the Asymmetric [4 + 2] Cycloaddition of In Situ‐Generated Dienes from Isochromane‐3,4‐Diones with Nitroalkenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Herein, the first asymmetric [4+2] cycloaddition is reported, utilizing in situ‐generated dienes from isochromane‐3,4‐diones and nitroalkenes, catalyzed by a bifunctional thiourea organocatalyst and Brønsted base cocatalysts, yielding highly enantioselective bridged and spiro lactones, with further investigations into novel reactivity and product ...
Mohammad Sadeq Mousavi   +2 more
wiley   +1 more source

Isochromene and Dihydroisobenzofuran Electrosynthesis by a Highly Regiodivergent Cyclization of 2-Ethynylbenzaldehydes. [PDF]

open access: yesJ Org Chem
Martins GM   +6 more
europepmc   +1 more source

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