Results 221 to 230 of about 397,176 (340)
A Ti(III) complex synthesized mechanochemically catalyzes the cycloaddition of CO2 (1 bar) with terminal, internal, and trisubstituted epoxides. Mechanistic studies by density functional theory calculations reveal that the superior activity of Ti(III) compared to Ti(IV) arises from its lower oxophilicity, facilitating CO2 insertion into Ti–O bonds, as ...
Elena Álvarez‐Ruiz+5 more
wiley +1 more source
Biomass-derived 5-(tolylmethyl)furfural as a promising diesel additive: preparation, process scale-up, and engine studies. [PDF]
Yadav AK+4 more
europepmc +1 more source
The liquidation features of accidents involving large-scale emissions of petroleum products
Yu. V. Zelenko, Chzhu Zhui
openalex +2 more sources
A series of amidines are prepared via PIII/PVO redox catalyzed in situ formation of imidoyl chlorides from amides. The desired products are obtained in good to excellent yields. Moreover, the protocol is applied to the synthesis of Erlotinib. Amidines are a ubiquitous class of bioactive compounds found in a wide variety of natural products; thus ...
Viktorija Medvarić+2 more
wiley +1 more source
Carbon Dioxide to Chemicals: CO<sub>2</sub> Conversion Enhancement over Ni<sub>3</sub>Ga/Cu-ZSM‑5 Composite Material. [PDF]
Aboghander MW+5 more
europepmc +1 more source
THE ORETICAL FOUNDATION FOR CALCULATION OF FLUID SYSTEMS IN THE SUBSURFACE CONTAMINATED WITH LIGHT PETROLEUM PRODUCTS DURING GROUNDWATER FLUCTUATION
Paper 3. Teoretical foundation for calculation of “air – light petroleum products – water” three-phase systems in porous media [PDF]
N.S. Ognianik, N.K. Paramonova
openalex +1 more source
A solvent‐free mechanochemical reduction of nitro compounds using hydrogen gas is presented. In addition to enabling the synthesis of a variety of functionalized aniline derivatives, the method has been scaled up to gram quantities, evaluated for trace metal impurities, and applied to the synthesis of pharmaceutical compounds and their precursors.
Samarth Bhatnagar+2 more
wiley +1 more source
Redrawing the Mannich‐Type Reaction through Carbonyl Umpolung Reactivity
GA: Herein, a conceptually novel one‐pot multicomponent strategy is reported for the streamlined construction of five‐membered imidazolidines from 1,2‐diaza‐1,3‐dienes (onefold), amines (twofold), and formaldehyde (twofold). This redesigned Mannich‐type reaction that exploits a carbene‐like activity of 1,2‐diaza‐1,3‐dienes (realized by “umpolung ...
Vittorio Ciccone+4 more
wiley +1 more source