Results 231 to 240 of about 397,176 (340)

Tunable Preparation of α‐Aminoacyl Fluorides and α‐Fluoroamides via Base‐Induced Cascade Multiple‐Cleavage Processes from Bromodifluorohydrin Reagents and Amines

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A mild and versatile strategy enabling the divergent synthesis of α‐fluoroamides and α‐aminoacyl fluorides from 2‐bromo‐2,2‐difluoro alcohols and amines is developed. The reaction shows broad scope and operational simplicity. Mechanistic and density functional theory studies support the formation of a putative gem‐difluoroepoxide intermediate ...
Giulia De Santis   +8 more
wiley   +1 more source

Potential Advances in the Design of Sealants for Geologic Conformance Control toward CO<sub>2</sub> Storage Security. [PDF]

open access: yesACS Omega
Afolabi F   +7 more
europepmc   +1 more source

Estimation of evaporative losses during storage of crude oil and petroleum products

open access: bronze, 2012
Marina Mihajlović   +3 more
openalex   +2 more sources

Visible‐Light‐Promoted Dearomatization for The Construction of Imidazole Scaffolds

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Lighting up flat aromatics: a visible‐light photocatalytic dearomative acylation of imidazo[1,2‐a]pyridines using α‐keto acids as sustainable acyl radical precursors is reported, leading to dual fluorescent imidazoles. Dearomatization is a powerful strategy for constructing complex carbocycles and heterocycles, though it typically relies on harsh ...
Silvia Roscales, Aurelio G. Csáky
wiley   +1 more source

One‐Pot Cascade Synthesis of Isoquinolinone‐Fused Quinoxalines Through Sequential Rh(III)/Pd(II) Catalysis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A new one‐pot, dual catalytic strategy for the synthesis of polycyclic isoquinolinone‐fused quinoxalines from commercially available N‐(2‐acetamidophenyl)benzamides and 1,3‐diynes is reported. This transformation proceeds via Rh(III)/Pd(II)‐mediated sequential NH/CH activation/annulation. Detailed mechanistic studies elucidate the reaction pathway. A
Wei‐Jung Chiu   +3 more
wiley   +1 more source

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