Towards Greener Synthesis of Substituted 3-Aminophthalates Starting from 2<i>H</i>-Pyran-2-ones via Diels-Alder Reaction of Acetylenedicarboxylates. [PDF]
Fendre D, Lukšič M, Kranjc K.
europepmc +1 more source
A mild and versatile strategy enabling the divergent synthesis of α‐fluoroamides and α‐aminoacyl fluorides from 2‐bromo‐2,2‐difluoro alcohols and amines is developed. The reaction shows broad scope and operational simplicity. Mechanistic and density functional theory studies support the formation of a putative gem‐difluoroepoxide intermediate ...
Giulia De Santis+8 more
wiley +1 more source
Potential Advances in the Design of Sealants for Geologic Conformance Control toward CO<sub>2</sub> Storage Security. [PDF]
Afolabi F+7 more
europepmc +1 more source
Estimation of evaporative losses during storage of crude oil and petroleum products
Marina Mihajlović+3 more
openalex +2 more sources
Visible‐Light‐Promoted Dearomatization for The Construction of Imidazole Scaffolds
Lighting up flat aromatics: a visible‐light photocatalytic dearomative acylation of imidazo[1,2‐a]pyridines using α‐keto acids as sustainable acyl radical precursors is reported, leading to dual fluorescent imidazoles. Dearomatization is a powerful strategy for constructing complex carbocycles and heterocycles, though it typically relies on harsh ...
Silvia Roscales, Aurelio G. Csáky
wiley +1 more source
Electrochemical synthesis of aziridines, pyrrolidines and oxazolines enabled by azo-free alcohol amination. [PDF]
Hale EA, Zhu Q.
europepmc +1 more source
Do carbenium ion additions toward alkenes proceed via .pi. complexes? A stereochemical investigation [PDF]
Mayr, Herbert+3 more
core +1 more source
A new one‐pot, dual catalytic strategy for the synthesis of polycyclic isoquinolinone‐fused quinoxalines from commercially available N‐(2‐acetamidophenyl)benzamides and 1,3‐diynes is reported. This transformation proceeds via Rh(III)/Pd(II)‐mediated sequential NH/CH activation/annulation. Detailed mechanistic studies elucidate the reaction pathway. A
Wei‐Jung Chiu+3 more
wiley +1 more source
Pd-Catalyzed Direct Diarylation of Sodium Hypophosphite Enables the Synthesis of Diarylphosphonates. [PDF]
Yang J, Qian D, Wang G, Yang S.
europepmc +1 more source