Radical‐Polar Crossover Bicyclization Enables a Modular Synthesis of Saturated Bicyclic Amines
Herein, we report the successful realization of a radical‐polar crossover bicyclization reaction from easily available cyclopropylamines and substituted alkenes through photoredox catalysis. This approach introduces an innovative methodology for the de novo synthesis of a diverse collection of 4/5‐, 5/5‐, 6/5‐,7/5‐ and 5/6‐fused saturated bicyclic ...
Dewei Feng+4 more
wiley +1 more source
Rh(III)-Catalyzed Double Annulation of 3-Phenyl-1,2,4-oxadiazoles with 2-Diazo-1,3-diketones: Access to Pyran-Fused Isoquinolines. [PDF]
Zhang E, Sun M, Gao L.
europepmc +1 more source
Sinter‐ and Water‐Resistant Pt Enabled by High Entropy of Porous Oxide Nanofibers
The high‐entropy effect thermodynamically favors a unique distribution of multiple constituent elements within the crystalline lattice with low Gibbs free energy. This special configuration endows the material with exceptional stability, depressing the growth of Pt species at elevated temperatures.
Yunpeng Wang+7 more
wiley +1 more source
Synthesis of Tricyclic and Tetracyclic Lactone Derivatives of Thieno[2,3-<i>b</i>]pyrazine or Thieno[2,3-<i>b</i>]quinoline: Preliminary Antitumor and Antiparasitic Activity Evaluation. [PDF]
Martins MF+6 more
europepmc +1 more source
Apparatus for Determining of the Pour Point of Crude Oil and Petroleum Products
A N Sokolnikov+2 more
openalex +1 more source
A unique interfacial conversion concept is proposed to establish robust cathode electrolyte interphase for stabilizing fluorinated polyanionic cathodes in aqueous electrolytes. In a typical case, the conformal Al2O3 sacrificial layer is predeposited on high‐voltage sodium vanadium oxy‐fluorophosphates cathode, which can progressively react with trace ...
Peng Gong+8 more
wiley +1 more source
Revitalization of Soil Contaminated by Petroleum Products Using Materials That Improve the Physicochemical and Biochemical Properties of the Soil. [PDF]
Wyszkowska J+3 more
europepmc +1 more source
The study develops a H•/H– transfer strategy enabling efficient hydrocyclization/defluorination of CF3‐acrylamides to synthesize Seletracetam derivatives with gem‐difluoroalkenes. Mechanistic studies reveal distinct pathways: the NiII‐H/PhSiH3 system operates through a hydrogen atom transfer process, while the 1,4‐Michael addition of H– appears to be ...
Yanjun Wan, Ronghui Shao, Jack R. Norton
wiley +1 more source
Development of benzofuran-derived sulfamates as dual aromatase-steroid sulfatase inhibitors (DASIs): design, synthesis and biological evaluation. [PDF]
Eissa AG+8 more
europepmc +1 more source