Results 131 to 140 of about 591,025 (333)

CO2‐to‐Cyclic Carbonate Transformation at Ambient Pressure Using a Mechanochemically Prepared Ti(III) Catalyst

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A Ti(III) complex synthesized mechanochemically catalyzes the cycloaddition of CO2 (1 bar) with terminal, internal, and trisubstituted epoxides. Mechanistic studies by density functional theory calculations reveal that the superior activity of Ti(III) compared to Ti(IV) arises from its lower oxophilicity, facilitating CO2 insertion into Ti–O bonds, as ...
Elena Álvarez‐Ruiz   +5 more
wiley   +1 more source

SECTORAL EFFECTS OF A WORLD OIL PRICE SHOCK: ECONOMYWIDE LINKAGES TO THE AGRICULTURAL SECTOR [PDF]

open access: yes
The effects of a world oil price shock on U.S. agriculture are analyzed in an economywide environment. We use an input-output model to analyze the direct and indirect cost linkages between energy and other sectors of the economy.
Hanson, Kenneth   +2 more
core   +1 more source

Synthesis of Amidines Via P(III)/P(V)O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A series of amidines are prepared via PIII/PVO redox catalyzed in situ formation of imidoyl chlorides from amides. The desired products are obtained in good to excellent yields. Moreover, the protocol is applied to the synthesis of Erlotinib. Amidines are a ubiquitous class of bioactive compounds found in a wide variety of natural products; thus ...
Viktorija Medvarić   +2 more
wiley   +1 more source

Production and Trade in Services by U.S. Multinational Firms [PDF]

open access: yes
Direct investment in foreign countries by U.S. goods industries represents a response to differences in labor costs to a much greater extent than the more rapidly growing investment by service industries.
Irving B. Kravis, Robert E. Lipsey
core  

Solvent‐Free Mechanocatalytic Reduction of Nitro Compounds with Hydrogen Gas and its Application in the Synthesis of Drugs and their Intermediates

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A solvent‐free mechanochemical reduction of nitro compounds using hydrogen gas is presented. In addition to enabling the synthesis of a variety of functionalized aniline derivatives, the method has been scaled up to gram quantities, evaluated for trace metal impurities, and applied to the synthesis of pharmaceutical compounds and their precursors.
Samarth Bhatnagar   +2 more
wiley   +1 more source

Redrawing the Mannich‐Type Reaction through Carbonyl Umpolung Reactivity

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
GA: Herein, a conceptually novel one‐pot multicomponent strategy is reported for the streamlined construction of five‐membered imidazolidines from 1,2‐diaza‐1,3‐dienes (onefold), amines (twofold), and formaldehyde (twofold). This redesigned Mannich‐type reaction that exploits a carbene‐like activity of 1,2‐diaza‐1,3‐dienes (realized by “umpolung ...
Vittorio Ciccone   +4 more
wiley   +1 more source

The Latin American and Caribbean Energy Review 2003 [PDF]

open access: yes
The 2003 Energy review,contains information about the 2003 energy situation of each of our member countries, regional data, as well as economic and social indicators corrected and extended through historical series.
Alejandro Villarreal   +4 more
core  

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