Results 291 to 300 of about 300,604 (345)

Spin‐Orbit Photonics with Potato Starch Lenses

open access: yesAdvanced Optical Materials, EarlyView.
Native potato starch spherulites are introduced as volumetric optical elements that modulate both dynamic and geometric phases of light. These spherulites focus light and generate optical vortices via spin‐orbit interaction, functioning as polarization‐sensitive microlenses. Their unique radial anisotropy enables applications in vortex beam generation,
Petr Bouchal   +4 more
wiley   +1 more source

Carbonized Polymer Dots‐Based Spectrally Adaptable Photonic Microbarcodes

open access: yesAdvanced Optical Materials, EarlyView.
This study explores spectrally tunable photonics barcodes using carbonized polymer dots (CPDs) based on whispering gallery mode (WGM) photoluminescence. CPDs offer wavelength‐dependent emission from visible to near‐infrared (NIR), thereby enabling variable WGM emissions.
Barun Kumar Barman   +2 more
wiley   +1 more source

Recyclable All‐in‐One Organo‐Photo‐Auxiliaries Enabling (sp3)C−(sp3)C Coupling Reactions with Diverse Functionalities

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 5, March 4, 2025.
Abstract Photochemical C−C coupling reactions can be tailored to industrial chemical processes and preparations of pharmaceuticals. Recent approaches in this area are limited to using precious transition metal coordination complexes that facilitate light absorption and redox processes with benchtop chemicals. Herein, we propose a paradigm that involves
Samjhana Maharjan   +9 more
wiley   +1 more source

Dual Lewis Acid Promoted/Visible Light Driven Preparation of Aryl Diazenyl Oxazoles from Isocyanoacetamides and Arylazo Sulfones

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 5, March 4, 2025.
Abstract While arylazo sulfones have been widely applied as arylating agents, their exploitation for diazenylation reactions has been previously limited to electron‐rich alkenes such as styrenes and silyl enol ethers. Herein we optimized a synthetic one‐pot protocol to access oxazolyl azo compounds via a selective domino ring‐closing/aryldiazenylation ...
Enzo Delalande   +5 more
wiley   +1 more source

Direct Access to α,β‐Unsaturated γ‐Lactams via Palladium‐Catalysed Carbonylation of Propargylic Ureas.

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 5, March 4, 2025.
Abstract Additive carbonylations typically necessitate strong nucleophiles, such as alcohols or amines. In this study, we carbonylated a poorly nucleophilic urea, under oxidant‐free conditions. Our straightforward carbonylative strategy enables access to versatile α,β‐unsaturated γ‐lactams featuring an aminocarbonyl fragment, utilizing readily ...
Debora Schiroli   +11 more
wiley   +1 more source

Constant Enzymatic in situ Production of H2O2 for an Unspecific Peroxygenase by an l–Amino Acid Oxidase

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Unspecific Peroxygenases have been the subject of a lot of research in the recent past as they offer opportunities for green hydroxylation reactions using hydrogen peroxide (H2O2) as donor. A striking problem of UPOs is their low stability against their own co‐substrate H2O2. In order to prevent the deactivation, we developed an enzyme cascade
Simon Last   +6 more
wiley   +1 more source

Asymmetric Synthesis of Highly Substituted Spiro[2H‐pyrrole‐2,3‐Succinimide] Derivatives by Copper‐Catalyzed Post‐Ugi Reactions

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Herein we present a novel one‐pot methodology for the synthesis of enantioenriched 2H‐pyrrolespirosuccinimides by copper‐catalyzed reactions on Ugi adducts derived from enantiopure α‐alkylbenzyl amines through a chirality transfer process. We have proposed a mechanism, supported by density functional theory (DFT) calculations, where a hydrogen
Javier Gómez‐Ayuso   +3 more
wiley   +1 more source

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