Engineered Metal–Organic Frameworks‐Based Materials for Environmental Detection
Engineered metal–organic frameworks (MOFs) regulated by various material modification strategies are discussed for environmental contaminant detection under different sensing mechanisms, providing future improvements of MOFs in environmental detection. Sensitive and selective detection of contaminants is crucial for environmental protection.
Pan Gao +3 more
wiley +1 more source
Development of an electrochemical maltose biosensor [PDF]
In this work, electrochemical maltose biosensors based on mutants of the maltose binding protein (MBP) are developed. A ruthenium II complex (Ru II ), which is covalently attached to MBP, serves as an electrochemical reporter of MBP conformational ...
García García, Alfonso +3 more
core +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
Structural and Bonding Properties of Uranium Complexes With Phenanthroline Ligands
In the field of spent nuclear fuel reprocessing, the recovery and utilization of uranium is of significant importance. Current research focuses primarily on the development of highly efficient actinide extractants.
Shuang LIANG, Lu ZHANG, Shuxian HU
doaj +1 more source
Synthesis and characterisation of ruthenium complexes containing a pendent catechol ring [PDF]
A series of [Ru(bipy)₂L]⁺ and [Ru(phen)₂L]⁺ complexes where L is 2-[5-(3,4-dimethoxyphenyl)-4H-1,2,4-triazol-3-yl]pyridine (HL1) and 4-(5-pyridin-2-yl-4H-1,2,4-triazol-3-yl)benzene-1,2-diol (HL2) are reported.
Adrian L. Guckian +58 more
core +1 more source
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Photoreductive Dissolution of Iron Oxides Trapped in Ice and Its Environmental Implications [PDF]
The availability of iron has been thought to be a main limiting factor for the productivity of phytoplankton and related with the uptake of atmospheric CO_2 and algal blooms in fresh and sea waters. In this work, the formation of bioavailable iron (Fe(II)
Choi, Wonyong +4 more
core +1 more source
Structural and Luminescence Properties of Silica-Based Hybrids Containing New Silylated-Diketonato Europium(III) Complex [PDF]
A new betadiketonate ligand displaying a trimethoxysilyl group as grafting function and a diketone moiety as complexing site (TTA-Si = 4,4,4-trifluoro-2-(3-trimethoxysilyl)propyl)-1-3-butanedione (C4H3S)COCH[(CH2)3Si(OCH3)3]COCF3) and its highly ...
Adriana P. Duarte +45 more
core +2 more sources
Chan–Lam Cross‐Coupling With Alkylboron Reagents: From Transmetallation to Radical Pathways
Alkylative Chan–Lam coupling overcomes intrinsic transmetallation limitations of alkylboron reagents by engaging radical pathways. Recent advances reveal how radical and radical–polar crossover mechanisms enable mild C(sp3)—heteroatom bond formation. This minireview highlights key mechanistic insights and emerging strategies that transform alkylboron ...
Nicolas G.‐Simonian +3 more
wiley +1 more source
Highly Active CH Bond Borylation of Aromatics With Pyridine as Convenient, Low-Cost Ligand Under Iridium Catalysis. [PDF]
The highly atom‐economy iridium‐catalyzed CH bond borylation of aromatics has been achieved utilizing simple and trivial pyridine as the ligand, which is 2–3 orders of magnitude cheaper than the current state‐of‐the‐art ligands, thus significantly reducing both the E‐factor and the carbon footprint associated with tedious and waste‐generating ligand ...
Delahaye V +4 more
europepmc +2 more sources

