For directly comparing experimental results on gas‐phase ion reactions with the predictions from quantum chemical calculations, the latter must first be converted into rate constants. This review addresses the question of whether current methods of statistical rate theory can accomplish this task reliably. Statistical rate theory has long been used for
Thomas Auth, Konrad Koszinowski
wiley +1 more source
Pd‐Catalyzed C─C Bond Borylation of Biphenylenes Leading to Tri‐Ortho‐Substituted Biaryls
Palladium‐catalyzed ring‐opening C─C borylation of 1‐substituted biphenylenes yields a range of o,o,o′‐trisubstituted biaryls with two ortho‐boryl groups via selective cleavage of the least hindered C─C bond. The resulting diborylated products are readily amenable to sequential, site‐selective postfunctionalization.
Robyn V. Presland +5 more
wiley +1 more source
A sustainable, ligand‐free Pd‐catalyzed borrowing hydrogen protocol in a biodegradable hydrophobic natural deep eutectic solvent (NADES) (thymol/DL‐menthol) enables the N‐alkylation of primary amines with benzylic alcohols under mild, aerobic conditions, allowing efficient reuse of both catalyst and solvent for seven consecutive cycles. The hydrophobic
Maryam Saeb +5 more
wiley +1 more source
Synthesis of chlorophyll b: a retrospective analysis of chlorophyllide a oxygenase. [PDF]
Hoober JK +3 more
europepmc +1 more source
A Bifunctional Small Molecule Degrader of the Long Noncoding RNA MALAT1 Triplex
Targeting disease‐linked RNAs with small molecules is often limited by the modest impact of binding RNA structure alone. Here, we present a first‐in‐class bifunctional molecule that degrades the oncogenic lncRNA MALAT‐1 by inducing proximity between the RNA and a cleaving warhead.
Christian A. T. Brega +12 more
wiley +1 more source
DNA/BSA binding, antidiabetic and antioxidant studies of copper(ii) complexes derived from <i>ONO</i>-tridentate Schiff bases and diimines as auxiliary ligands. [PDF]
Oladipo SD +4 more
europepmc +1 more source
Cyclometalated Rhodium(III) Polypyridyl Complexes with Anti-Cancer Stem Cell Activity. [PDF]
Ren H, Singh K, Suntharalingam K.
europepmc +1 more source
Mixed Phenanthroline-Bipyridine Europium and Ytterbium Cryptates─Bright Luminophores with Small Radiative Lifetimes. [PDF]
Haas T +6 more
europepmc +1 more source
Water-Soluble Palladium Complexes with 1,10-Phenanthroline-Synthetic Aspects, Crystal Structure, DNA-Binding and In Vitro Antibacterial Evaluation. [PDF]
Uvarova MA +5 more
europepmc +1 more source
One-Shot SERRS Detection of Iron and Acidity in Aqueous Systems. [PDF]
Calderón González I +6 more
europepmc +1 more source

