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1,10-Phenanthroline

2012
[66-71-7] C12H8N2 (MW 180.21) InChI = 1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H InChIKey = DGEZNRSVGBDHLK-UHFFFAOYSA-N (reagent used as supporting ligand in a wide variety of metal-catalyzed processes) Alternate Name: Phen. Physical Data: mp 100–104 °C. Solubility: soluble in alcohol, acetone, ether,
Arkaitz Correa, Ruben Martin
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Preparation of Chiral 5,6‐trans‐Disubstituted Phenanthrolines from Phenanthroline‐5,6‐epoxide.

ChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
Elke Schoffers   +2 more
openaire   +1 more source

Electrochemistry of iridium chelates with phenanthroline or substituted phenanthroline and cyclooctadiene

Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1989
The electrochemistry of a series of indium chelates with phenanthroline or substituted phenanthroline and cyclooctadiene on Hg, Pt, Au and glassy carbon electrodes is reported. Two quasi-reversible one-electron reductions between −0.8 and −1.1 V and between −1.25 and −1.55 V vs. a saturated calomel electrode were studied. Adsorption and a slow chemical
COSTA, GIACOMO   +4 more
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Synthesis of Hemiprotonic Phenanthroline–Phenanthroline+ Compounds with both Antitumor and Antimicrobial Activity

Journal of Medicinal Chemistry, 2022
Currently, cancer patients with microbial infection are a severe challenge in clinical treatment. To address the problem, we synthesized hemiprotonic compounds based on the unique structure of hemiprotonic nucleotide base pairs in a DNA i-motif. These compounds were produced from phenanthroline (ph) dimerization with phenanthroline as a proton receptor
Zizhen Zhao   +9 more
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Liquid-crystalline phenanthrolines

Journal of Materials Chemistry, 2001
The synthesis and mesomorphism of the first liquid-crystalline phenanthrolines are reported.
Sandrine J. P. Bousquet, Duncan W. Bruce
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DNA Interaction of Platinum(II) Complexes with 1,10-Phenanthroline and Extended Phenanthrolines

Inorganic Chemistry, 2005
The interaction with DNA of the platinum(II) square planar complexes [Pt(N-N)(py)(2)](2+) (N-N = 1,10-phenanthroline (phen), dipyrido[3,2-d:2',3'-f]quinoxaline (dpq), dipyrido[3,2-a:2',3'-c]phenazine (dppz), benzodipyrido[b:3,2-h:2'3'-f]phenazine (bdppz)) has been investigated by means of absorption, circular and linear dichroism spectroscopy, DNA ...
CUSUMANO, Matteo   +2 more
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Basizität der Phenanthroline

Berichte der Bunsengesellschaft für physikalische Chemie, 1973
AbstractDie pK‐Werte und die thermodynamischen Daten der beiden möglichen protolytischen Gleichgewichte der Phenanthroline (P)magnified imagewurden aus der pH‐ und Temperaturabhängigkeit ihrer Elektronenanregungsspektren bestimmt. Die theoretisch zu erwartende lineare Korrelation zwischen pk‐Wert‐Differenzen und reziproken Stickstoffabständen wird ...
Th. Bluhm, H.‐H. Perkampus, J. V. Knop
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Two phenanthroline hydrochlorides

Acta Crystallographica Section C Crystal Structure Communications, 2000
The crystal and molecular structures of two phenanthroline hydro­chlorides have been determined at 173 K. 1,10-Phenanthrolin-1-ium chloride, C12H9N2+·Cl−, crystallizes in two stacks of exactly planar mol­ecules. Both stacks are approximately parallel to the (\bar{2}02) plane and the planes composing the different stacks enclose an angle of 13.29 (3 ...
, Hensen, , Spangenberg, , Bolte
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Diaquamalonato(1,10-phenanthroline)zinc(II)

Acta Crystallographica Section C Crystal Structure Communications, 2005
In the crystal structure of the title complex, [Zn(C3H2O4)(C12H8N2)(H2O)2], the Zn(II) atom displays a distorted octahedral geometry, being coordinated by two N atoms from the 1,10-phenanthroline ligand, two O atoms from different carboxylate groups of the chelating malonate dianion and two O atoms of cis water molecules.
Xu Cheng, Fu   +3 more
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Enantiopure Chiral Concave 1,10‐Phenanthrolines

European Journal of Organic Chemistry, 2016
AbstractChiral information has been introduced into concave 1,10‐phenanthrolines of different ring sizes by using a 2,7‐disubstituted naphthalene bridgehead, which causes axial chirality. A tetraphenolic 2‐(dihydroxynaphthyl)‐9‐(dihydroxyphenyl)‐1,10‐phenanthroline was synthesized as a key intermediate.
Reck, Lisa M.   +2 more
openaire   +1 more source

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