Results 111 to 120 of about 12,918 (277)
Enantioselective aminoarylation of ortho‐allyl anilines is achieved under mild conditions. Key to success is the electrostatically‐directed nature of the key aminopalladation step, achieved by using the sulfonated chiral ligand sSPhos on palladium. A detailed study of electronic trends allows tuning of the sulfonamide protecting group to enable good ...
Max Kadarauch +4 more
wiley +2 more sources
Substituição nucleofílica aromática em 1,2-dicloro-4,5-dinitrobenzeno com aminas [PDF]
TCC (graduação) - Universidade Federal de Santa Catarina. Centro de Ciências Físicas e Matemáticas. Curso de Química.O 1,2-dicloro-4,5-dinitrobenzeno, DCDNB, reage com aminas primárias em condições de temperatura e pressão ambientes, formando produtos ...
Ricardo, Juan
core
Photochemical rearrangement of benzylenol ethers
Evidence is presented for the structures of the products isolated from the light-induced rearrangement of benzylenol ethers of Δ4-3-oxo-steroids. The products obtained on irradiation of benzyl vinyl ether indicate that the rearrangement proceeds by ...
K Schaffner, JT Pinhey
core +1 more source
A non‐contact computer vision method enables monitoring and quantitative comparison of vessel‐specific CO release kinetics from structurally diverse surrogates in two‐chamber COware reactors, revealing that surrogate reactivity scores correlate with carbonylation reaction outcomes.
Kristin Donnachie +4 more
wiley +2 more sources
A highly efficient palladium-catalyzed asymmetric tandem aza-Heck/Sonogashira coupling reaction of O-phenyl hydroxamic ethers with terminal alkynes is described.
Han, Ying +6 more
core +1 more source
A series of 3-nitrophenyl and 3-hydroxyphenyl ethers of (S)-N-methylprolinol bearing bulky and lipophilic substituents at phenyl C5 were tested for affinity at α4β2 and α3β4 nAChRs. The two phenyl ethers 5-substituted with 6-hydroxy-1-hexynyl showed high
F. Bavo +6 more
core +1 more source
Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey +4 more
wiley +2 more sources
Isomerisation of Optically Active Ethers.
Ethers of the general formula CHR[2].OR' re-arrange under the influence of Lewis bases such as phenyl lithium into their isomeric alcohols CR[2].R'OH.
Norula, Jagdish Lal.
core
Isomerisation of Optically Active Ethers.
Ethers of the general formula CHR[2].OR' re-arrange under the influence of Lewis bases such as phenyl lithium into their isomeric alcohols CR[2].R'OH.
Norula, Jagdish Lal.
core
Pd-Catalyzed Synthesis of Allylic Silanes from Allylic Ethers
Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes.
Bruce H. Lipshutz (1330881) +2 more
core +1 more source

