Results 11 to 20 of about 37,076 (287)

Gas-Phase Pyrolytic Reaction of 4-Aryl-3-buten-2-ols and Allyl Benzyl Ethers: Kinetic and Mechanistic Study

open access: yesMolecules, 2010
Flash vacuum pyrolysis (FVP) of 4-aryl-3-buten-2-ols [ArCH=CH-CH(CH3)OH, where Ar is phenyl, p-MeO, p-Me, p-Cl, p-NO2] gave the corresponding buta-1,3-dien-1-ylbenzene (ArCH=CH-CH=CH2, where Ar is Ph, p-MeO, p-Me, p-Cl, p-NO2) and 7-X-1,2 ...
Maher R. Ibrahim   +3 more
doaj   +1 more source

Catalysis by alkali and alkaline-earth metal ions in nucleophilic attack of methoxide ion on crown ethers bearing an intra-annular acetoxy group [PDF]

open access: yes, 1989
Rates of reaction of methoxide ion with crown ethers bearing an intra-annular acetoxy group are markedly enhanced by alkali and alkaline-earth metal bromides as a result of much stronger interactions of the metal ions with transition states than with ...
Cacciapaglia, Roberta   +5 more
core   +3 more sources

The Reaction of Trimethylsilylethynyl(phenyl)iodonium Triflate with Some Phenolates: Formation of Substitution and sp2 C-H Insertion Products

open access: yesMolecules, 2000
Treatment of trimethylsilylethynyl(phenyl)iodonium triflate with the potassium salts of some acidic phenols results in the formation of substitution products (O-trimethylsilylethynylphenols and/or O-ethynylphenols), along with sp2C-H insertion products ...
Anastasios Varvoglis   +2 more
doaj   +1 more source

Two-step degradable ABAC-type periodic poly(cyclic acetal)s synthesized by sequence-programmed monomer formation and subsequent polyaddition based on cyclotrimerization of one vinyl monomer and two aldehydes

open access: yesGiant, 2023
ABAC-type periodic poly(cyclic acetal)s were synthesized via a two-step method consisting of the synthesis of a sequence-programmed cyclic trimers from one vinyl monomer and two bifunctional aldehydes (isophthalaldehyde or terephthalaldehyde) and the ...
Tadashi Naito   +2 more
doaj   +1 more source

Profiling of oligolignols reveals monolignol coupling conditions in lignifying poplar xylem [PDF]

open access: yes, 2004
A
Morreel, Kris   +7 more
core   +2 more sources

A TGA/FTIR and Mass Spectral Study on the Thermal Degradation of Bisphenol A Polycarbonate [PDF]

open access: yes, 2004
The thermal degradation of polycarbonate under nitrogen was studied using TGA/FTIR, GC/MS and LC/MS as a function of mass loss. The gases evolved during degradation were inspected by in situ FTIR and then the evolved products were collected and analysed ...
Jang, Bok Nam, Wilkie, Charles A.
core   +2 more sources

Triazolinediones as highly enabling synthetic tools [PDF]

open access: yes, 2016
Triazolinediones (TADs) are unique reagents in organic synthesis that have also found wide applications in different research disciplines, in spite of their somewhat "exotic" reputation.
Billiet, Stijn   +5 more
core   +1 more source

Synthesis of 2-phenylamino-thiazole derivatives as antimicrobial agents

open access: yesJournal of Saudi Chemical Society, 2017
A series of 10 new N-phenyl-4-(4-(thiazol-2-yl)-phenyl)-thiazol-2-amine derivatives (3a–j) and 4 new 5-(2-(phenylamino)-thiazol-4-yl)-benzamide ethers (3′a–d) were synthesized from 4-(2-phenylamino)-thiazol-4-yl)-benzothioamide and 2-hydroxy-5-(2 ...
Dominique Serge Ngono Bikobo   +6 more
doaj   +1 more source

In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers [PDF]

open access: yes, 2008
Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes2Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic ...
Hayes, Douglas.   +2 more
core   +1 more source

Anti-Larval and Anti-Algal Natural Products from Marine Microorganisms as Sources of Anti-Biofilm Agents

open access: yesMarine Drugs, 2022
Bacteria growing inside biofilms are more resistant to hostile environments, conventional antibiotics, and mechanical stresses than their planktonic counterparts.
Kai-Ling Wang   +5 more
doaj   +1 more source

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