The Honey Volatile Code: A Collective Study and Extended Version
Background: The present study comprises the second part of a new theory related to honey authentication based on the implementation of the honey code and the use of chemometrics.
Ioannis K. Karabagias +2 more
doaj +1 more source
Efficient cationic ring-opening polymerization of diverse cyclic imino ethers: unexpected copolymerization behavior [PDF]
The recently developed fast microwave-assisted cationic ring-opening polymerization procedure for 2-oxazolines seems to be ideally suited for slower polymerizing cyclic imino ether monomers.
Bloksma, Meta M +6 more
core +2 more sources
Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source
Reactions of cyclobutenones with nucleophilic reagents via vinylketen intermediates [PDF]
While strong nucleophiles add to the endocyclic double bond of cyclobutenones to yield cyclobutanones, weaker nucleophiles (e.g. alcohols, aniline) interact with the vinylketens which are thermally or photochemically generated from cyclobutenones; the ...
Huisgen, Rolf, Mayr, Herbert
core +1 more source
Eutectozymes as Soft Hybrid Materials for Advanced Biocatalysis
Eutectozymes are sustainable hybrid materials that embed a GOx–HRP cascade within hydrophobic eutectogels featuring a dual supramolecular–covalent network. This architecture preserves native enzyme structure and stability, enables efficient heterogeneous biocatalysis in aqueous media, and positions eutectogels as robust platforms for next‐generation ...
Manuel Eduardo Martinez Cartagena +10 more
wiley +1 more source
Regioselectivity of the Claisen Rearrangement of Meta- and Para-Substituted Allyl Aryl Ethers
The regioselectivity of the Claisen rearrangement with different meta-substituted and meta- and para-substituted allyl phenyl ethers was investigated.
William Thomas Möller +3 more
doaj +1 more source
Asymmetric Electrophilic alpha-Amidoalkylation, VII1): Generation, Crystal Structure, and Trapping Reactions of a Chiral 6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoline Derived N-Acyliminium Ion [PDF]
The camphanic acid amide 4 has efficiently been oxidized with triphenylcarbenium tetrafluoroborate (3) to yield the chiral N-acyliminium ion 1. Trapping reactions of 1 with the silyl nucleophiles 7a-c and 10a-f proceeded with stereoselective bond ...
Aledesanmi +15 more
core +1 more source
Reaction Products of Cyanoalkyl Phenyl Ethers and Carboxyalkyl Phenyl Ethers with Formaldehyde
過塩素酸を触媒とし, 酢酸溶媒を用い置換アルキルフェニルエーテル (C6H5O(CH2)nX, X=CN, COOH : n=1,3,4) とホルムアルデヒドとの反応をおこない, 生成する可溶性樹脂の分子量におよぼすXとnの影響について調べた。その結果を下記に記す。ニトリル基を有する化合物の樹脂構造は主としてメチレン結合とメチレンビスアミド結合, カルボキシル基を有する樹脂は主としてメチレン結合によって連結されているものと推定された。
Akira NINAGAWA +3 more
openaire +2 more sources
Functional Metal Complexes for Solar–Light‐Driven Energy Conversion
This review provides an exhaustive summary of the recent advancements of functional metal complexes in solar‐to‐electrical, ‐chemical, and ‐thermal energy conversion, comprising material categories, design strategies, underlying principles of operation, and identified improvement of performances.
Yanyan Qin +3 more
wiley +1 more source
Protonation and ring closure of stereoisomeric alpha-substituted cinnamic acids in superacidic media studied by 13C NMR spectroscopy and computations [PDF]
Five alpha-substituted cinnamic acids [(E)- and (Z)-2,3-diphenyl-, (E)- and (Z)-3-(2-methoxyphenyl)-2-phenyl- and (E)-2-(2-methoxyphenyl)-3-phenyl-propenoic acids] have been protonated in fluorosulfonic acid at -78 degrees C, Protonation of the ...
Burrichter, Arwed +5 more
core +1 more source

