Results 1 to 10 of about 186,275 (344)
New ferrocene-derived hydroxymethylphosphines: FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and the dppf analogue 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵-C₅H₄)₂] [PDF]
Reactions of the ferrocene-phosphines FcPH₂ and 1,1′-Fc′(PH₂)₂ with excess formaldehyde gives the new hydroxymethylphosphines FcP(CH₂OH)₂ 1 and 1,1′-Fc′[P(CH₂OH)₂]₂ 2, respectively. Phosphine 1 is an air-stable crystalline solid, whereas 2 is isolated as
Alley, Steven R., Henderson, William
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The Living ROMP of trans-Cyclooctene [PDF]
The living ring-opening metathesis polymerization (ROMP) of trans-cyclooctene (tCO) was investigated. ROMP of tCO in the presence of PPh_3 in THF leads to the formation of narrowly dispersed polycyclooctene (PCO).
Conrad, Rosemary M. +2 more
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Susceptibility of phosphine-resistant cigarette beetles to various insecticides
Management of phosphine resistance in the cigarette beetle Lasioderma serricorne (F.) has become a topic of great interest to the tobacco industry in recent years.
Fukazawa, Naoto
doaj +1 more source
Electrophysiological and molecular mechanisms of protection by iron sucrose against phosphine-induced cardiotoxicity: A time course study [PDF]
The present study was designed for determining the exact mechanism of cytotoxic action of aluminum phosphide (AlP) in the presence of iron sucrose as the proposed antidote.
Abdollahi, M. +8 more
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Cycloaurated triphenylphosphine-sulfide and –selenide [PDF]
The first examples of cycloaurated phosphine sulfides and triphenylphosphine selenide have been synthesised; these complexes are fairly rare examples of gold(III) complexes with potentially reducing sulfur- and selenium-donor ligands.
Henderson, William +2 more
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Recent developments in the global application of ECO2FUME® and VAPORPH3OS® phosphine fumigants
ECO2FUME® (2% phosphine, 98% CO₂ by weight) and VAPORPH3OS® (99.3% phosphine average by weight) are cylinderized gas formulations of phosphine that have achieved significant growth in commercial applications for the disinfestation of food and non-food ...
Tumambing, Justin +3 more
doaj +1 more source
Control of postharvest pest on cocoa beans during storage is generally conducted by fumigation with phosphine. Long-term exposure to phosphine and improper fumigation practices could stimulate the development of resistant strains against phosphine.
Sri Widayanti +2 more
doaj +1 more source
Chiral separation of substituted phenylalanine analogues using chiral palladium phosphine complexes with enantioselective liquid–liquid extraction [PDF]
Chiral palladium phosphine complexes have been employed in the chiral separation of amino acids and phenylalanine analogues in particular. The use of (S)-xylyl-BINAP as a ligand for the palladium complex in enantioselective liquid–liquid extraction ...
Adriaan J. Minnaard +47 more
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Phosphine is the only general use fumigant for the protection of stored grain, though its long-term utility is threatened by the emergence of highly phosphine-resistant pests.
Saad M Alzahrani, Paul R Ebert
doaj +1 more source
In the present study, the distribution of phosphine gas in a cylindrical silo was modeled and compared with available sensor data. The cylindrical silo was filled with wheat and a recirculation system was used to enhance the diffusion of phosphine ...
Kaloudis, Efstathios +4 more
doaj +1 more source

