Results 151 to 160 of about 186,275 (344)
Advanced Intelligent Discovery, EarlyView.Two‐photon polymerization enables high‐resolution microfabrication, but performing alignment when printing multiple structures is difficult. Here, we present a fast, robust, and open‐source protocol for automated alignment on Nanoscribe systems. Achieving ≈0.4 μm accuracy in under 5 s, our protocol reduces time and error in multimaterial printing. This
Daniel Maher +4 more
wiley +1 more source
Angewandte Chemie, EarlyView.A Pd‐catalyzed regioselective synthesis of benzylsilanols from Kobayashi‐type reagents has been developed through a mechanistically distinct approach involving 1,4‐Pd migration followed by intramolecular transmetalation. The reaction can be combined with various prior transition‐metal‐catalyzed processes and the resulting benzylsilanols have been ...
Ryo Shintani, Keisuke Tachibana
wiley +2 more sources
Advanced Intelligent Systems, EarlyView.This study provides an introduction to Bayesian optimisation targeted for experimentalists. It explains core concepts, surrogate modelling, and acquisition strategies, and addresses common real‐world challenges such as noise, constraints, mixed variables, scalability, and automation.
Chuan He +2 more
wiley +1 more source
Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides
Angewandte Chemie, EarlyView.A phosphorus ylide‐mediated strategy achieves the direct fixation of nitrous oxide (N2O) to access diazo compounds, which after intra‐ or intermolecular trapping, afford N2‐containing organic building blocks. This approach provides an alternative to hazardous diazo‐transfer reagents and establishes N2O fixation as a sustainable methodology.
Jhen‐Kuei Yu +4 more
wiley +2 more sources
Advanced Intelligent Systems, EarlyView.In this article, we develop bespoke resins for stereolithography 3D‐printing of soft‐robotic grippers that are controlled remotely by electrothermal stimulus near ambient temperatures. Turning on the electrical control, each finger can be actuated separately.
Kalyan Ghosh +4 more
wiley +1 more source
Azide‐to‐Diazo Transformation Facilitated by Michael Addition via Phosphazide Formation
Angewandte Chemie, EarlyView.A new type of Michael addition based on azide‐to‐diazo conversion is disclosed. This unusual transformation proceeds via 1,4‐addition accompanied by N─N bond cleavage of phosphazide intermediates under practical conditions. The high versatility of the resulting Michael adducts enables the synthesis of a wide variety of organonitrogen compounds ...
Tomoki Mano +3 more
wiley +2 more sources
Concentric Rheostat Decoupled 3D Force‐Sensing Module for Smart Table Tennis Training
Advanced Intelligent Systems, EarlyView.A 3D‐printed sensor array intrinsically decouples normal and shear forces through a unique concentric structural design. By integrating piezoresistive, sliding area‐varying capacitive, and concentric rheostat mechanisms, the 12‐sensor module achieves high‐resolution 3D force mapping without complex algorithms.
Zhe Liu +7 more
wiley +1 more source
Cobalt‐Catalyzed Intramolecular C─H Silylation of Arenes
Angewandte Chemie, EarlyView.Direct C─Si bond formation via C─H silylation is an atom‐economical route to organosilanes but is largely limited to noble metals. We report the first cobalt‐catalyzed intramolecular arene C–H silylation enabled by HCo(PMe3)4, which activates Si–H and C–H bonds to form diverse silacycles and silafluorenes in high yields with broad functional‐group ...
Yongqiang Xu +4 more
wiley +2 more sources
Angewandte Chemie, EarlyView.RhI dimers with bridging aryl isocyanide and di‐phosphine ligands show NIR‐I or NIR‐II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh‐Rh interactions can be tuned by peripheral modification of the aryl isocyanide ligand, resulting in a rigid Rh2 core and improved photophysical properties ...
Vanitha R. Naina +4 more
wiley +2 more sources