Partial Hydrogenation of Aryl-Substituted Benzothiophenes, Benzofurans and Indoles by Photocatalytic Water Activation. [PDF]
JACS AuMayska R, Studer A.
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Borane‐Catalyzed Water Dehydrogenation at Dioxaphospholes and ‐Phospholanes
Angewandte Chemie International Edition, EarlyView.The borane‐catalyzed dehydrogenation of phenylphosphinate esters, which are formed from the reaction of dioxaphospholes and ‐phospholanes with water or air moisture under mild conditions, is reported. The mechanism of this transformation was investigated by kinetic measurements and DFT calculations, which indicate hydrogen elimination from a ...
Niklas Koch +4 more
wiley +1 more source
Divergent construction of Ni and Fe-Al-H assemblies.
Chem Commun (Camb)Gipper JR +3 more
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Solvent-Controlled Chemoselectivity in Brønsted Acidic Deep Eutectic Mixtures: A Metal-Free One-Pot Cascade Meyer-Schuster/C-P Bond Formation. [PDF]
ChemSusChemMorís-Menéndez G +4 more
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Angewandte Chemie International Edition, EarlyView.The straightforward conversion of alcohols to tertiary or secondary amines employing Nms‐amides in a single operation is described. The transformation features broad functional group tolerance and high stereospecificity, underscoring its utility in the synthesis of isotope‐labeled pharmaceuticals.
Jakub Brześkiewicz +3 more
wiley +1 more source
Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride. [PDF]
Angew Chem Int Ed EnglWeiß CSV, Dabringhaus P.
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Atroposelective Bromination for the Synthesis of Chiral Biaryl Phosphines via Cross-Assembled Catalysis with Chiral Phosphoric Acid and Achiral Phenol. [PDF]
J Am Chem SocYu Z, Yang H, Wong MW, Yeung YY.
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Water, Alcohols, Amines, and Amides as Formal Hydrogen-Atom-Transfer Reagents Through Activation With Redox-Active Lewis Acids. [PDF]
Angew Chem Int Ed EnglVojáčková P, Studer A.
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Angewandte Chemie International Edition, EarlyView.Renewable guaiacols are rapidly oxidized by phenyliodine(III)diacetate to masked ortho‐quinones, giving a new class of monomers that undergo selective Michael‐type polyaddition with multithiols to from thiol‐guaiacol connectivity‐bearing polymers. The activation applies to discrete monomers and directly to lignin, enabling two‐component adhesives that ...
Dominik P. Hoch +7 more
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Cycloaddition Reactions of Sulfo-Biginelli Derived Thiadiazines. [PDF]
Org LettHill CL, Sambor M, Yang A, Wipf P.
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