Results 231 to 240 of about 186,275 (344)

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

European Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair, Marc‐Etienne Moret, Luke A. Wilkinson, Adrian B. Chaplin   +3 more
wiley   +1 more source

The organophosphorus synthesis triangle: introducing methods for the missing quaternization and de-quaternization routes. [PDF]

Chem Sci
Vetter AC, Ortin Y, Nikitin K, Gilheany DG.   +3 more
europepmc   +1 more source

Expanded Scorpionate and Siderophore‐Inspired Ligands: From Foundational Designs to Modern Applications

European Journal of Inorganic Chemistry, EarlyView.
The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley, Trandon Allen Bender   +1 more
wiley   +1 more source

Investigation of Acoramidis-based ionic liquids as potential stabilizers of transthyretin using DFT calculations, molecular docking, and ADMET studies. [PDF]

Sci Rep
Mostaghni F, Mahani NM.
europepmc   +1 more source

Phosphorescent Platinum(II) Complexes With Diazinedipyrrolide Pincer Ligands: Structure and Photophysical Properties

European Journal of Inorganic Chemistry, EarlyView.
A new family of phosphorescent Pt(II) complexes with pyrimidinedipyrrolide ligands, including a pyrazine analog, was designed and synthesized. Their emission properties can be finely tuned via ligand modification, revealing strong phosphorescence originating from intraligand charge transfer transitions.
Marcela Horáková, Alexandre Rico, Filip Bureš, Pascal le Poul, Sébastien Gauthier, Jiří Váňa, Zdeňka Růžičková, Sylvain Achelle   +7 more
wiley   +1 more source

Electronic and Steric Effects of the ProPhos Ligand Family for Nickel-Catalyzed Suzuki-Miyaura Coupling of Heteroaromatics. [PDF]

ACS Catal
Yang J, Zhao H, Schultz JE, Wisniewski SR, Simmons EM, Diao T.   +5 more
europepmc   +1 more source

Stereochemical Modulation of Palladacyclopentadienyl Complexes Bearing Diphosphine Ligands: A Key to Enhanced DNA Interaction and Anticancer Activity

European Journal of Inorganic Chemistry, EarlyView.
A modular library of structurally robust palladacyclopentadienyl Pd(II) complexes bearing achiral and chiral diphosphines was developed, revealing a strong influence of diphosphine design and ligand chirality on cytotoxicity and selectivity against ovarian cancer cells, including platinum‐resistant models.
Stefania Mautone, Martina Scianna, Isabella Caligiuri, Laura Orian, Pablo Nogara, Nicola Demitri, Flavio Rizzolio, Thomas Scattolin   +7 more
wiley   +1 more source

"Blebbing" of a Gold Nanocluster by Dioxygen Insertion into Thiolate Staples during Self-Photooxidation. [PDF]

J Phys Chem A
Essang S, Greer A.
europepmc   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source